Abstract
Magneto-optical experiments are reported which demonstrate the influence of the structural phase transition in Pb1−xGexTe (x<0.012) on the band structure. Cyclotron resonance has been observed both above and below Tc. Above Tc the band structure is similar to that of PbTe with four equivalent valleys at the L-point in both conduction and valence bands. At Tc a rhombohedral phase transition occurs and the valleys are split into a singly degenerate (T) valley and three equivalent (L) valleys. The effective masses and relative band-edge energies for the different types of valley are deduced.
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Lewis, A.V., Bauer, G., Nicholas, R.J. et al. The band structure of Pb1−x Ge x Te above and below the structural phase transition. Int J Infrared Milli Waves 1, 485–499 (1980). https://doi.org/10.1007/BF01007328
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DOI: https://doi.org/10.1007/BF01007328