Abstract
Solubilities of potassium tetraphenylborate in water, methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-octanol at 15, 25, 35, 45, 55°C have been determined by spectrophotometry. The standard Gibbs energy of transfer of potassium tetraphenylborate form water to straightchain n-alkanols and the medium effect of potassium tetraphenylborate from 15 to 55°C have been calculated. Furthermore, the contribution of microscopic interactions to the standard Gibbs energy of transfer of potassium tetraphenylborate is calculated and discussed.
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Zou, LZ., Wang, Xl., Zhou, BX. et al. Standard Gibbs energies of transfer of potassium tetraphenylborate from water to straight-chain n-alkanols. J Solution Chem 24, 499–509 (1995). https://doi.org/10.1007/BF01004480
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DOI: https://doi.org/10.1007/BF01004480