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Radicals on surfaces formed by ionizing radiation

  • Part II: Structure And Reactivity Of Radicals On Surfaces
  • Published:
Molecular Engineering

Abstract

An overview is presented of radicals generated on porous metal oxide surfaces such as zeolites whose main source of generation has been ionizing radiation. Attention is primarily paid to ESR studies on structures and reactions of organic neutral and ionic radicals. A short introduction is also given to paramagnetic metal ions and clusters formed in zeolites and other related materials.

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References

  1. A. Lund and M. Shiotani (Eds.):Radical Ionic Systems. Properties in Condensed Phases, Kluwer Academic Publishers, Dordrecht (1991).

    Google Scholar 

  2. L. B. Knight, Jr.: ‘Generation and study of inorganic cations in rare gas matrices by electron spin resonance’, in A. Lund and M. Shiotani (Eds.),Radical Ionic Systems. Properties in Condensed Phases, Kluwer Academic Publishers, Dordrecht (1991).

    Google Scholar 

  3. P. P. Edwards, L. L. Woodall, P. A. Anderson, A. R. Armstrong, and M. Slaski:Chem. Soc. Rev. 305 (1993).

  4. K. B. Yoon:Chem. Rev. 93, 321 (1993).

    Google Scholar 

  5. J. Sohma and M. Shiotani:Magnetic Resonance in Colloidal and Interface Science: ACS Symposium Series,34, 141 (1976).

    Google Scholar 

  6. M. Shiotani, F. Yuasa, and J. Sohma:J. Phys. Chem. 79, 2669 (1975).

    Google Scholar 

  7. S. Kudo, A. Hasegawa, T. Komatsu, M. Shiotani, and J. Sohma:Chem. Lett. 705 (1973).

  8. K. Toriyama, K. Nunome, and M. Iwasaki:J. Am. Chem. Soc. 109, 4496 (1987).

    Google Scholar 

  9. L. B. Knight, Jr., J. Steadman, D. Feller, and E. R. Davidson:J. Am. Chem. Soc. 106, 3700 (1984).

    Google Scholar 

  10. S. Kubota, M. Iwaizumi, and T. Isobe:Bull. Chem. Soc. Jpn. 44, 2684 (1971).

    Google Scholar 

  11. T. Katsu, M. Yanagida, and Y. Fujita:J. Phys. Chem. 75, 4064 (1971).

    Google Scholar 

  12. Y. Fujita, T. Katsu, M. Sato, and K. Takahashi:J. Chem. Phys. 61, 4307 (1974).

    Google Scholar 

  13. K. Hatano, N. Shimamoto, T. Katsu, and T. Fujita:Bull. Chem. Soc. Jpn. 47, 4 (1974).

    Google Scholar 

  14. K. Toriyama, K. Nunome, and M. Iwasaki:J. Chem. Phys. 77, 5891 (1982).

    Google Scholar 

  15. G. Dolivo and A. Lund:J. Phys. Chem. 89, 3977 (1985).

    Google Scholar 

  16. M. Lindgren, A. Lund, and G. Dolivo:Chem. Phys. 99, 103 (1985).

    Google Scholar 

  17. M. Shiotani, M. Lindgren, F. Takahashi, and T. Ichikawa:Chem. Phys. Lett. 170, 201 (1990).

    Google Scholar 

  18. M. V. Barnabas, D. W. Werst, and A. D. Trifunac:Chem. Phys. Lett. 204, 435 (1993).

    Google Scholar 

  19. M. V. Barnabas, D. W. Werst, and A. D. Trifunac:Chem. Phys. Lett. 187, 565 (1991).

    Google Scholar 

  20. V. I. Melekhov, O. A. Anisimov, L. Sjöqvist, and A. Lund:Chem. Phys. Lett. 174, 95 (1991).

    Google Scholar 

  21. M. Lindgren, M. Matsumoto, and M. Shiotani:J. Chem. Soc., Perkin Trans. II, 1397 (1992).

  22. V. A. Bol'shov and A. M. Volodin:React. Kinet. Catal. Lett. 43, 87 (1991).

    Google Scholar 

  23. C. J. Rhodes:J. Chem. Soc., Chem. Commun. 13, 900 (1991).

    Google Scholar 

  24. Ch. Gullyev, L. A. Surina, S. A. Surin, and G. D. Chukin:Neftekhimiya 30(4), 492 (1990) (Russ).

    Google Scholar 

  25. V. A. Bol'shov and A. M. Volodin:React. Kinet. Catal. Lett. 46, 337 (1992).

    Google Scholar 

  26. M. K. Carter and G. Vincow:J. Chem. Phys. 47, 292 (1967).

    Google Scholar 

  27. T. R. Tuttle, and S. I. Weissman:J. Am. Chem. Soc. 80, 3542 (1958).

    Google Scholar 

  28. O. Edlund, P.-O. Kinell, A. Lund, and A. Shimizu:J. Phys. Chem. 46, 3679 (1967).

    Google Scholar 

  29. T. Komatsu, A. Lund, and P.-O. Kinell:J. Phys. Chem. 76, 1721 (1972).

    Google Scholar 

  30. M. Iwasaki, K. Toriyama, and K. Nunome:J. Chem. Soc., Chem. Commun. 320 (1983).

  31. R. Erickson, M. Lindgren, A. Lund, and L. Sjöqvist:Colloids and Surfaces A:72, 207 (1993).

    Google Scholar 

  32. D. G. Streets and G. P. Ceaser:J. Phys. Chem. 66, 257 (1977).

    Google Scholar 

  33. J. D. Clark and D. C. Frost:J. Am. Chem. Soc. 89, 244 (1967).

    Google Scholar 

  34. J. C. Vedrineet al.:J. Catalysis 59, 248 (1979).

    Google Scholar 

  35. D. N. Stamieres and J. Turkevich:J. Am. Chem. Soc. 86, 749 (1964).

    Google Scholar 

  36. A. E. Hirchler, W. C. Neikam, D. S. Barmby, and R. L. James:J. Catal. 4, 628 (1965).

    Google Scholar 

  37. S. Shih:J. Catal. 79, 390 (1983).

    Google Scholar 

  38. T. Ichikawa, M. Yamaguchi, and H. Yoshida:J. Phys. Chem. 91, 6400 (1987).

    Google Scholar 

  39. M. V. Barnabas and A. D. Trifunac:J. Chem. Soc., Chem. Commun. 813 (1993).

  40. P. L. Corio and S. Shih:J. Phys. Chem. 75, 3475 (1971).

    Google Scholar 

  41. C. J. Rhodes:J. Chem. Soc., Faraday Trans. 87, 3179 (1991).

    Google Scholar 

  42. R. Crockett and E. Roduner:J. Chem. Soc., Perkin Trans II (1993).

  43. C. J. Rhodes and M. Standing:J. Chem. Soc., Perkin Trans II, 1455 (1992).

  44. M. V. Barnabas, D. W. Werst, and A. D. Trifunac:Chem. Phys. Lett. 206, 21 (1993).

    Google Scholar 

  45. M. V. Barnabas and A. D. Trifunac:Chem. Phys. Lett. 193, 298 (1992).

    Google Scholar 

  46. X. Z. Qin and A. D. Trifunac:J. Phys. Chem. 95, 6466 (1991).

    Google Scholar 

  47. M. Shiotani and K. Ohta: unpublished results.

  48. C. Periera, G. T. Kokotalio, and R. J. Gorte:J. Phys. Chem. 95, 705 (1991).

    Google Scholar 

  49. S. D. Cox and G. D. Stucky:J. Phys. Chem. 95, 710 (1991).

    Google Scholar 

  50. S. Bordiga, G. Ricchiardi, G. Spoto, D. Scarano, L. Carnelli, A. Zecchina, and C. O. Arean:J. Chem. Soc., Faraday Trans. 89, 1843 (1993).

    Google Scholar 

  51. M. Shiotani and K. Yamaji: unpublished results.

  52. P. H. Kasai:J. Chem. Phys. 43, 3322 (1965).

    Google Scholar 

  53. J. A. Rabo, C. L. Angell, P. H. Kasai, and V. Schomaker:J. Chem. Soc., Disc. Faraday Soc. 41, 328 (1966).

    Google Scholar 

  54. P. H. Kasai and R. J. Bishop, Jr.:J. Phys. Chem. 77, 2308 (1973).

    Google Scholar 

  55. P. H. Kasai and R. J. Bishop, Jr.:J. Am. Chem. Soc. 94, 5560 (1972).

    Google Scholar 

  56. P. P. Edwards, M. R. Harrison, J. Klinowski, S. Ramdas, J. M. Thomas, D. C. Johnson, and C. J. Page:J. Chem. Soc., Chem., Commun. 982 (1984).

  57. M. R. Harrison:J. Solid. State Chem. 54 (1984).

  58. R. E. H. Breuer, E. de Boer, and G. Geismar:Zeolites 9, 336 (1989).

    Google Scholar 

  59. P. A. Anderson, R. J. Singer, and P. P. Edwards:J. Chem. Soc., Chem. Commun. 914 (1991).

  60. P. A. Anderson and P. P. Edwards:J. Chem. Soc., Chem. Commun. 915 (1991).

  61. Y. Kim, Y. W. Han, and K. Seff:J. Phys. Chem. 97, 12663 (1993).

    Google Scholar 

  62. S. H. Song, U. S. Kim, Y. Kim, and K. Seff:J. Phys. Chem. 96, 10937 (1992).

    Google Scholar 

  63. S. H. Song, Y. Kim, and K. Seff:J. Phys. Chem. 95, 9919 (1991).

    Google Scholar 

  64. M. S. Jeong, Y. Kim, and K. Seff:J. Phys. Chem. 97, 10139 (1993).

    Google Scholar 

  65. L. R. M. Martens, P. J. Grobet, and P. A. Jacobs:Nature 315, 568 (1985).

    Google Scholar 

  66. B. Xu and L. Kevan:J. Phys. Chem. 96, 2642 (1992).

    Google Scholar 

  67. B. Xu, X. Chen, and L. Kevan:J. Chem. Soc., Faraday Trans. 87, 3157 (1991).

    Google Scholar 

  68. B. Xu and L. Kevan:J. Phys. Chem. 96, 3647 (1992).

    Google Scholar 

  69. K. B. Yoon and J. K. Kochi:J. Chem. Soc., Chem. Commun. 510 (1988).

  70. G. A. Kuranova:High Energy Chem. 91, 25 (1992).

    Google Scholar 

  71. X. Liu and J. K. Thomas:Chem. Phys. Lett. 192, 555 (1992).

    Google Scholar 

  72. P. A. Andersson, D. Barr, and P. P. Edwards:Angew. Chem. Intern. Ed. Engl. 30, 1551 (1991).

    Google Scholar 

  73. K.-K. Iu, X. Liu, and J. K. Thomas:J. Phys. Chem. 97, 8165 (1993).

    Google Scholar 

  74. L. Shields:Trans. Faraday. Soc. 62, 1042 (1966).

    Google Scholar 

  75. C. E. Forbes and M. C. R. Symons:Mol. Phys. 27, 467 (1974). A. D. Stevens and M. C. R. Symons:Chem. Phys. Lett. 109, 514 (1984).

    Google Scholar 

  76. J. A. Howard, K. F. Preston, and B. Mile:J. Am. Chem. Soc. 103, 6226 (1981).

    Google Scholar 

  77. J. A. Howard, R. Sutcliffe, and B. Mile:J. Phys. Chem. 87, 2268 (1983). K. Kernisant, G. A. Thompson, and D. M. Lindsay:J. Chem. Phys. 82, 4739 (1985).

    Google Scholar 

  78. H. K. Beyer, P. A. Jacobs, and J. B. Uytterhoeven:J. Chem. Soc., Faraday Trans. 72, 674 (1976).

    Google Scholar 

  79. P. A. Jacobs, J. P. Linart, H. Nijs, J. B. Uytterhoeven, and H. K. Beyer:J. Chem. Soc., Faraday Trans. 73, 1745 (1977).

    Google Scholar 

  80. P. A. Jacobs, J. B. Uytterhoeven, and H. K. Beyer:J. Chem. Soc., Faraday Trans. I.73, 1755 (1977).

    Google Scholar 

  81. P. A. Jacobs and J. B. Uytterhoeven:J. Chem. Soc., Faraday Trans. I.75, 56 (1979).

    Google Scholar 

  82. L. R. Gellens, W. J. Mortier, R. A. Schoonheydt, and J. B. Uytterhoeven:J. Phys. Chem. 85, 2783 (1981).

    Google Scholar 

  83. L. R. Gellens, W. J. Mortier, and J. B. Uytterhoeven:Zeolites 1, 11 (1981).

    Google Scholar 

  84. G. A. Ozin, M. D. Baker, and J. Godber:J. Phys. Chem. 88, 4902 (1984).

    Google Scholar 

  85. M. D. Baker. G. A. Ozin, and J. Godber:J. Phys. Chem. 89, 305 (1985).

    Google Scholar 

  86. J. Texter, R. Kellermann, and T. Gonsiorowski:J. Phys. Chem. 90, 2118–24 (1986).

    Google Scholar 

  87. L. R. Gellens, W. J. Mortier, R. A. Schoonheydt, and J. B. Uytterhoeven:J. Phys. Chem. 85, 2783 (1981).

    Google Scholar 

  88. D. Hemmerschmidt and R. Haul:Ber. Bunsen-Ges. Phys. Chem. 84, 902 (1980).

    Google Scholar 

  89. Y. Kim and K. Seff:J Am. Chem. Soc. 100, 6989 (1978).

    Google Scholar 

  90. J. R. Morton and K. F. Preston:J. Magn. Reson. 68, 121 (1986).

    Google Scholar 

  91. J. R. Morton and K. F. Preston:Zeolites 7, 2 (1987).

    Google Scholar 

  92. J. R. Morton, K. F. Preston, A. Sayari, and J. S. Tse:J. Phys. Chem. 91, 2117 (1987).

    Google Scholar 

  93. P. Grobet and R. A. Schoonheydt:Surf. Sci. 156, 893 (1985).

    Google Scholar 

  94. R. A. Schoonheydt and H. Leeman:J. Phys. Chem. 93, 2048 (1989).

    Google Scholar 

  95. J. Michalik and L. Kevan:J. Am. Chem. Soc. 108, 4247 (1986).

    Google Scholar 

  96. M. Narayana, A. S. W. Li, and L. Kevan:J. Phys. Chem. 85, 132 (1981).

    Google Scholar 

  97. M. Narayana and L. Kevan:J. Chem. Phys. 76, 3999 (1982).

    Google Scholar 

  98. A. van der Pol, E. J. Reijerse, E. de Boer, T. Wasowicz, and J. Michalik:Mol. Phys. 75, 37 (1992).

    Google Scholar 

  99. T. Wasowicz and J. Michalik:Radiat. Phys. Chem. 37, 427 (1991).

    Google Scholar 

  100. J. Michalik, A. van der Pol, E. J. Reijerse, T. Wasowicz, and E. de Boer:Appl. Magn. Reson. 3, 19 (1992).

    Google Scholar 

  101. J. Michalik, T. Wasowicz, J. Sadlo, and A. van der Pol:Colloids and Surfaces A 72, 81 (1993).

    Google Scholar 

  102. C. Cros and J.-C. Benejat:Bull. Soc. Chim. France 5, 1739 (1972).

    Google Scholar 

  103. C. Cros, M. Pouchard, and P. Hagenmuller:J. Sol. State. Chem. 2, 570 (1970).

    Google Scholar 

  104. A. F. Hebard, M. J. Rosseinsky, R. C. Haddon, D. W. Murphy, S. H. Glarum, T. T. Palstra, A. P. Ramirez, and A. R. Kortan:Nature 350, 600 (1991).

    Google Scholar 

  105. S. B. Roy, K. E. Sim, and A. D. Caplin:Philisophical Magazine B 65, 1445 (1992).

    Google Scholar 

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Shiotani, M., Lindgren, M. Radicals on surfaces formed by ionizing radiation. Mol Eng 4, 179–199 (1994). https://doi.org/10.1007/BF01004054

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