Abstract
EPR spectroscopy is a powerful tool to identify at a molecular level, the different steps of catalyst preparation, and of catalytic reactions:
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(i)
Deposition of paramagnetic transition metal ions onto a support is monitored, and the coordination sphere of the metallic center is characterized by EPR.
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(ii)
The catalyst is also characterized after activation (thermal oxidation or reduction):
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- the distribution among the different sites in zeolites can be determined;
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- the dispersion of the active phase may be appreciated;
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- the unsaturation degree of the active site may be evaluated using probe molecules such as water or13C enriched carbon monoxide.
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(iii)
The catalytic mechanisms can be investigated by studying the elementary steps of the catalytic reaction, as illustrated for methanol oxidation over Mo/SiO2 catalysts whose EPR results have extended the reaction mechanism proposed on the basis of kinetic data. In addition, reaction intermediates may be isolated inquasi-in situ conditions as in the case of olefin oligomerization catalyzed by Ni/SiO2 systems.
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Louis, C., Lepetit, C. & Che, M. EPR characterization of oxide supported transition metal ions: Relevance to catalysis. Mol Eng 4, 3–38 (1994). https://doi.org/10.1007/BF01004048
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DOI: https://doi.org/10.1007/BF01004048