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Transition Metal Chemistry

, Volume 19, Issue 6, pp 646–650 | Cite as

Gold(III) complexes with imidazole, benzoxazole, purine and pyrimidine derivatives

  • Dušan J. Radanović
  • Zoran D. Matović
  • Gustavo Ponticelli
  • Paola Scano
  • Inessa A. Efimenko
Full Papers

Summary

The synthesis and characterization of AuIII complexes with several heterocyclic ligands are reported. The compounds have general formula [AuX3(L)], where L =N-methylimidazole (N-MeIz),N-ethylimidazole (N-EtIz),N-propylimidazole (N-PrIz), benzoxazole (BO), 2-methylbenzoxazole (2-MeBO), 2,5-dimethylbenzoxazole (2,5-diMeBO), 2-amino-pyrimidine (2-APm), 4(6) -hydroxy-pyrimidine [4(6)-hydrPm] or hypoxanthine (Hypox) and X = Cl or Br. Elemental analysis, conductivity measurements and spectral studies were used for the characterization of the complexes. A square-planar geometry withN-bonded heterocyclic ligands is suggested.

Keywords

Gold Inorganic Chemistry Catalysis Imidazole Pyrimidine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman & Hall 1994

Authors and Affiliations

  • Dušan J. Radanović
    • 1
  • Zoran D. Matović
    • 1
  • Gustavo Ponticelli
    • 2
  • Paola Scano
    • 3
  • Inessa A. Efimenko
    • 4
  1. 1.Department of ChemistryFaculty of Science, University of KragujevacKragujevacYugoslavia
  2. 2.Dipartimento di Chimica e Tecnologie Inorganiche e MetallorganicheUniversità di CagliariCagliariItaly
  3. 3.Dipartimento di Science ChimicheUniversità di CagliariCagliariItaly
  4. 4.N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia

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