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Transition Metal Chemistry

, Volume 19, Issue 6, pp 603–605 | Cite as

Electrochemical synthesis of benzoylglycine and ethylphthaloyl-glycine complexes of transition metal ions

  • Ahmed A. El-Asmy
  • Medhat A. Hafez
  • Eman M. Saad
  • Fatma I. Taha
Full Papers

Summary

The direct electrochemical oxidation of metallic iron, cobalt, nickel and copper in Me2CO solution of benzoylglycine and/or ethylphthaloylglycine gave products with high yields. For each of the complexes, the electrochemical efficiency is commensurate with the metals being divalent. Conventional physical and chemical studies were used to characterize the isolated complexes and octahedral geometry was suggested for them on the basis of magnetic and electronic spectral studies. The i.r. spectra show that the ligands coordinate in a bidentate fashion; the carboxylate ion is monodentate. The molar conductances agree with the complexes being non-electrolytes.

Keywords

Nickel Cobalt Catalysis Carboxylate Spectral Study 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman & Hall 1994

Authors and Affiliations

  • Ahmed A. El-Asmy
    • 1
  • Medhat A. Hafez
    • 1
  • Eman M. Saad
    • 1
  • Fatma I. Taha
    • 1
  1. 1.Chemistry Department, Faculty of ScienceMansoura UniversityMansouraEgypt

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