Abstract
Enthalpic pairwise interaction parameters, hjj, were determined by titration calorimetry at 25°C for dilute solutions of glycerol, D-threitol, manitol, and D-glucitol in water. The parameters for these and other polyols conform to the expression hjj (J-kg−1)=145+135nOH−21.5n 2OH −41.7 2dl -160.5ndlld, where nOH=nC is the number of hydroxyl groups (carbon atoms), ndl is the number of dl configuration of a vicinal pair of OH-groups, and ndlld is the number of such configurations in the polyol molecules. A rationalization of this expression is given.
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Soldi, L.G., Marcus, Y., Blandamer, M.J. et al. Titration calorimetric determination of the pairwise interaction parameters of glycerol, D-threitol, mannitol, and D-glucitol in dilute aqueous solutions. J Solution Chem 24, 201–209 (1995). https://doi.org/10.1007/BF00979189
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DOI: https://doi.org/10.1007/BF00979189