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Electrochemical oxidation of aldoximes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The electrochemical oxidation of aldoximes was found to proceed with the loss of one electron and formation of the corresponding iminoxyl radical, which undergoes subsequent chemical reactions more rapidly than undergoing oxidation on the electrode.

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Literature cited

  1. V. A. Petrosyan, M. E. Niyazymbetov, and é. V. Ul'yanova, Izv. Akad. Nauk SSSR, Ser. Khim., No. 7, 1683 (1989).

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  2. J. L. Brokenshire, J. R. Roberts, and K. U. Ingold, J. Am. Chem. Soc.,94, 7040 (1972).

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  3. C. K. Mann and K. K. Barnes, Electrochemical Reactions in Nonaqueous Systems, Dekker, New York (1970).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Petrosyan, M. E. Niyazymbetov & é. V. Ul'yanova

Authors
  1. V. A. Petrosyan
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  2. M. E. Niyazymbetov
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  3. é. V. Ul'yanova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1687–1691, July, 1989.

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Petrosyan, V.A., Niyazymbetov, M.E. & Ul'yanova, é.V. Electrochemical oxidation of aldoximes. Russ Chem Bull 38, 1548–1551 (1989). https://doi.org/10.1007/BF00978458

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  • DOI: https://doi.org/10.1007/BF00978458

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