Electrochemical oxidation of ketoximes

  • V. A. Petrosyan
  • M. E. Niyazymbetov
  • é. V. Ul'yanova
Brief Communications


The oxidation of ketoximes on a platinum anode in acetonitrile proceeds through the intermediate formation of the corresponding radical-cation, iminoxyl radical, and oxoimmonium cation.


Oxidation Platinum Acetonitrile Electrochemical Oxidation Intermediate Formation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    Z. Galus, Theoretical Foundations of Chemical Electroanalysis, PWN, Warsaw, Poland (1971).Google Scholar
  2. 2.
    Yu. V. Pleskov and V. Yu. Filinovskii, The Rotating Disk Electrode [in Russian], Khimiya, Moscow (1976).Google Scholar
  3. 3.
    J. M. Kolthoff, J. Am. Chem. Soc.,79, 6110 (1957).Google Scholar
  4. 4.
    D. Serve, Electrochim. Acta,20, 469 (1975).Google Scholar
  5. 5.
    W. Summermann and U. Deffner, Tetrahedron,31, 593 (1975).Google Scholar
  6. 6.
    G. I. Shchukin, V. A. Ryabinin, I. A. Grigor'ev, and L. B. Volodarskii, Zh. Obshch. Khim.,56, 855 (1986).Google Scholar
  7. 7.
    J. L. Brockenshire, J. R. Roberts, and K. U. Ingold, J. Am. Chem. Soc.,94, 7040 (1972).Google Scholar
  8. 8.
    M. E. Niyazymbetov, V. A. Petrosyan, V. V. Semenov, and S. A. Shevelev, Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1333 (1981).Google Scholar
  9. 9.
    J. M. Kliegman and R. K. Barnes, J. Org. Chem.,37, No. 25, 4223 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • V. A. Petrosyan
    • 1
  • M. E. Niyazymbetov
    • 1
  • é. V. Ul'yanova
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

Personalised recommendations