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Problem of second and higher electron affinity of chemical compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Hexafluorides may have a positive second electron affinity, i.e., their doubly-charged anions may be stable toward the loss of an electron.

  2. 2.

    Species with maximum possible second and higher electron affinity should be sought among polynuclear MnkXnk+1 compounds, where k is the maximal formal valence of atom M and X is a monovalent electronegative ligand.

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Literature cited

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Chernogolovka Branch, Academy of Sciences of the USSR, Russia

    G. L. Gutsev & A. I. Boldyrev

Authors
  1. G. L. Gutsev
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  2. A. I. Boldyrev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1679–1682, July, 1989.

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Gutsev, G.L., Boldyrev, A.I. Problem of second and higher electron affinity of chemical compounds. Russ Chem Bull 38, 1541–1543 (1989). https://doi.org/10.1007/BF00978456

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  • DOI: https://doi.org/10.1007/BF00978456

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