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Polarity, polarizability, and structure of esters. 5. Phenyl formates

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    p-Substituted phenyl formates exist in solution in CCl4 at 25‡C in the form of an equilibrium mixture of 90±10% Z conformers and 10±10% E conformers with respect to the esteric group.

  2. 2.

    Phenyl formates are characterized in solutions by the rotation of the phenyl ring through ∿65‡ relative to the common plane of the molecule.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, Kazan Branch, Russia

    A. A. Bredikhin, L. V. Frolova & A. N. Vereshchagin

Authors
  1. A. A. Bredikhin
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  2. L. V. Frolova
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  3. A. N. Vereshchagin
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1560–1564, July, 1989.

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Bredikhin, A.A., Frolova, L.V. & Vereshchagin, A.N. Polarity, polarizability, and structure of esters. 5. Phenyl formates. Russ Chem Bull 38, 1426–1430 (1989). https://doi.org/10.1007/BF00978432

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  • DOI: https://doi.org/10.1007/BF00978432

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