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Conformation of molecules and electron-donor properties of certain representatives of tetrakis(alkylthio)- and tetrakis-(alkylsulfonyl)ethylenes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The relatively small values of the dipole moments of tetrakis(alkylthio)- and also of tetrakis(alkylsulfonyl)ethylenes indicate a certain structural symmetry of the molecules, and are possibly due to divergence of the SR groups from the plane of the central fragment.

  2. 2.

    In the reaction with group III metal halides, tetrakis(alkylthio)ethylenes display properties of polyfunctional electron-donors giving complexes with a 1∶1, 1∶2 composition and others with a more complex stoichiometry. Heats of formation and dipole moments of these complexes have been determined.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    E. S. Isaeva, N. E. Dontsova, N. P. Petukhova, E. N. Prilezhaeva & E. N. Gur'yanova

Authors
  1. E. S. Isaeva
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  2. N. E. Dontsova
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  3. N. P. Petukhova
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  4. E. N. Prilezhaeva
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  5. E. N. Gur'yanova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1552–1555, July, 1989.

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Isaeva, E.S., Dontsova, N.E., Petukhova, N.P. et al. Conformation of molecules and electron-donor properties of certain representatives of tetrakis(alkylthio)- and tetrakis-(alkylsulfonyl)ethylenes. Russ Chem Bull 38, 1419–1422 (1989). https://doi.org/10.1007/BF00978430

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  • DOI: https://doi.org/10.1007/BF00978430

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