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Spontaneous explosive decomposition of vinyl sulfoxide complexes of Fe3+, Cr3+, and Co3+ nitrates

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The phenomenon of spontaneous decomposition of complexes of Fe3+, Cr3+ and Co3+ with butyl vinyl sulfoxide during their synthesis, storage, or polymerization was observed. The observed thermal explosion is explained by spontaneous polymerization of sterically organized monomeric precursors formed as a result of self-association of the corresponding complexes.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Scientific Center, Ural branch, Academy of Sciences of the USSR, Ufa

    V. A. Nikonov, A. V. Kurochkin & G. V. Leplyanin

Authors
  1. V. A. Nikonov
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  2. A. V. Kurochkin
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  3. G. V. Leplyanin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1504–1505, July, 1989.

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Nikonov, V.A., Kurochkin, A.V. & Leplyanin, G.V. Spontaneous explosive decomposition of vinyl sulfoxide complexes of Fe3+, Cr3+, and Co3+ nitrates. Russ Chem Bull 38, 1374–1376 (1989). https://doi.org/10.1007/BF00978421

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  • DOI: https://doi.org/10.1007/BF00978421

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