Conclusions
-
1.
Gigantic palladium clusters and palladium black effectively catalyze the formation of acetals from carbonyl compounds and alcohols.
-
2.
Comparison of the acid properties of the clusters, Pd-black and mononuclear complexes of palladium(II) indicates that aprotic acid centers of the catalyst participate in the reaction.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
M. N. Vargaftik, V. P. Zagorodnikov, I. P. Stolyarov, et al., Dokl. Akad. Nauk SSSR,284, No. 4, 896 (1985).
V. P. Zagorodnikov, M. N. Vargaftik, D. I. Kochubei, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 849 (1989).
V. P. Zagorodnikov and M. N. Vargaftik, Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2652 (1985).
L. A. Yanovskaya, S. S. Yufit, and V. F. Kucherov, The Chemistry of Acetals [in Russian], Nauka, Moscow (1975), p. 54.
F. A. J. Meskens, Synthesis, No. 7, 501 (1981).
D. Y. Waddan, U. K. Patent No. 1,046,608 (1965).
F. Basolo and R. G. Pearson, Mechanism of Inorganic Reactions, 2nd ed., Wiley, New York (1967).
S. E. Livingstone, J. Chem. Soc., No. 12, 5091 (1957).
A. V. Nikiforova, I. I. Moiseev, and Ya. K. Syrkin, Zh. Obshch. Khim.,33, No. 10, 3239 (1963).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1495–1499, July, 1989.
Rights and permissions
About this article
Cite this article
Zagorodnikov, V.P., Vargaftik, M.N., Lyubimov, A.P. et al. Formation of acetals from carbonyl compounds and alcohols in the presence of gigantic palladium clusters and palladium black. Russ Chem Bull 38, 1366–1369 (1989). https://doi.org/10.1007/BF00978419
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00978419