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Alkylaromatic carbene ions on H-TsVK zeolites

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The adsorption of styrene (298 K), triphenylcarbinol (298 K), and of propylene with toluene (473 K) on H-TsVK zeolite leads to the formation of alkylaromatic carbocations which are stable up to 473–573 K and are characterized by bands in DRS at 320–330 and 400–440 nm and in IR by vC=C of the aromatic ring in the regions 1500 and 1610–1620 cm−1. In the adsorption of benzene, toluene, isopropylbenzene, and 1,3-dimethylnaphthalene at 298 K, only weakly bonded surface complexes are formed.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1486–1490, July, 1989.

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Demidov, A.V., Davydov, A.A. & Kurina, L.N. Alkylaromatic carbene ions on H-TsVK zeolites. Russ Chem Bull 38, 1357–1361 (1989). https://doi.org/10.1007/BF00978417

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  • DOI: https://doi.org/10.1007/BF00978417

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