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Structural properties of lead vanadate glasses containing La3+ or Fe3+ ions

Abstract

Structural properties of lead vanadate glasses containing La3+ or Fe3+ ions were investigated using X-ray diffraction, Fourier transform infrared spectroscopy and laser Raman spectroscopy. Crystalline Pb2V2O7 was formed for the molar composition 66.7PbO-33.3V2O5. Incorporation of greater quantities of La3+ into lead metavanadate glass caused the crystallization of Pb2V2O7. Fourier transform infrared and laser Raman spectra also suggested the presence of LaVO4. Incorporation of Fe3+ ions into lead metavanadate glass, up to 20 wt% Fe2O3, did not cause crystallization inside the glass matrix. Changes in the vibrational spectra are discussed.

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Musić, S., Gotić, M., Popović, S. et al. Structural properties of lead vanadate glasses containing La3+ or Fe3+ ions. J Mater Sci 29, 1227–1232 (1994). https://doi.org/10.1007/BF00975069

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Keywords

  • Polymer
  • Crystallization
  • Fourier Transform
  • Fe2O3
  • Fourier Transform Infrared Spectroscopy