Skip to main content
SpringerLink
Log in

Structural properties of lead vanadate glasses containing La3+ or Fe3+ ions

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Structural properties of lead vanadate glasses containing La3+ or Fe3+ ions were investigated using X-ray diffraction, Fourier transform infrared spectroscopy and laser Raman spectroscopy. Crystalline Pb2V2O7 was formed for the molar composition 66.7PbO-33.3V2O5. Incorporation of greater quantities of La3+ into lead metavanadate glass caused the crystallization of Pb2V2O7. Fourier transform infrared and laser Raman spectra also suggested the presence of LaVO4. Incorporation of Fe3+ ions into lead metavanadate glass, up to 20 wt% Fe2O3, did not cause crystallization inside the glass matrix. Changes in the vibrational spectra are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. A. Fotiev, B. V. Slobodin andM. Ya. Khodos, “Vanadates, Composition, Synthesis, Structure, Properties” (Nauka, Moscow, 1988) 272 pp. (in Russian).

    Google Scholar 

  2. V. A. Gubanov, D. E. Ellis andA. A. Fotiev,J. Solid State Chem. 21 (1977) 303.

    Google Scholar 

  3. M. Sayer andA. Mansingh,Phys. Rev. B6 (1972) 4629.

    Google Scholar 

  4. A. Tsuzuki, S. Kawakami, M. Awano, T. Sekiya andY. Torii,J. Mater. Sci. Lett. 7 (1988) 745.

    Google Scholar 

  5. E. Suoninen, E. Minni andI. M. Curelaru,J. Microsc. Spectrosc. Electron. 6 (1981) 1.

    Google Scholar 

  6. G. Calestani, A. Montenero, F. Pigoli andM. Bettinelli,J. Solid State Chem. 59 (1985) 357.

    Google Scholar 

  7. B. V. Slobodin, V. A. Zhilyev, N. V. Kiseleva, Y. N. Blinovskov,Zh. Neorg. Khim. 31 (1986) 268.

    Google Scholar 

  8. G. Calestani, G. D. Andreetti, A. Montenero andM. Bettinelli,Acta Crystallogr. C41 (1985) 177.

    Google Scholar 

  9. G. Calestani, G. D. Andreetti, A. Montenero M. Bettinelli andJ. Rebizant,ibid. C41 (1985) 179.

    Google Scholar 

  10. B. D. Jordan andC. Calvo,Can. J. Chem. 52 (1974) 2701.

    Google Scholar 

  11. E. Baiocchi, M. Bettinelli, A. Montenero andL. D. Sipio,J. Solid State Chem. 43 (1982) 63.

    Google Scholar 

  12. F. Momo, A. Sotgiu, E. Baiocchi, M. Bettinelli andA. Montenero,J. Mater. Sci. 17 (1982) 3221.

    Google Scholar 

  13. E. Agostinelli, P. Filaci, D. Fiorani, A. Montenero andM. Bettinelli,J. Non-Cryst. Solids 84 (1986) 329.

    Google Scholar 

  14. T. R. Gilson, O. F. Bizri andN. Cheetham,J. Chem. Soc. Dalton (1973) 291.

  15. P. Clauws andJ. Vennik,Phys. Status Solidi (b) 76 (1976) 707.

    Google Scholar 

  16. L. Abello, E. Husson, Y. Repelin andG. Lucazeau,Spectrochim. Acta 39A (1983) 641.

    Google Scholar 

  17. C. Sanchez, J. Livage, J. P. Audiere andA. Madi,J. Non-Cryst. Solids 65 (1984) 285.

    Google Scholar 

  18. J. C. Pedregosa, E. J. Baran andP. J. Aymonino,Z. Anorg. Allg. Chem. 404 (1974) 308.

    Google Scholar 

  19. L. V. Kristallov, A. A. Fotiev, L. A. Perelyaeva andM. P. Cvetkova,Zh. Neorg. Khim. 30 (1985) 3202.

    Google Scholar 

  20. V. Dimitrov andY. Dimitriev,J. Non-Cryst. Solids 122 (1990) 133.

    Google Scholar 

  21. E. J. Baran andP. J. Aymonino,Z. Anorg. Allg. Chem. 383 (1971) 220.

    Google Scholar 

  22. Idem, ibid. 383 (1971) 226.

    Google Scholar 

  23. O. Yamaguchi, Y. Mukaida, H. Shigeta, H. Takemura andM. Yamashita,Mater. Lett. 7 (1988) 158.

    Google Scholar 

  24. T. Nishida, M. Ogata andY. Takashima,Bull. Chem. Soc. Jpn 60 (1987) 2887.

    Google Scholar 

  25. T. Nishida, S. Saruwatari andY. Takashima,ibid. 61 (1988) 2343.

    Google Scholar 

  26. V. Dimitrov, Y. Dimitriev andV. Mihailova,Monatsh. Chem. 114 (1983) 669.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ruđer Bošković Institute, P. O. Box 1016, 41001, Zagreb, Republic of Croatia

    S. Musić, M. Gotić, S. Popović, K. Furić & V. Mohaček

  2. Department of Physics, Faculty of Science, University of Zagreb, P. O. Box 162, 41001, Zagreb, Republic of Croatia

    S. Popović

Authors
  1. S. Musić
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Gotić
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Popović
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. Furić
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. Mohaček
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Musić, S., Gotić, M., Popović, S. et al. Structural properties of lead vanadate glasses containing La3+ or Fe3+ ions. J Mater Sci 29, 1227–1232 (1994). https://doi.org/10.1007/BF00975069

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00975069

Keywords

Search

Navigation