Abstract
Viscosities of ternary liquid mixtures containing benzene + cyclohexane + carbon tetrachloride and the three possible binary combinations were measured at 25°C, and the excess viscosities were computed. Theoretical expressions for viscosity were developed on the basis of the Flory theory, the significant structure theory and a theory based on a method of estimating the properties of multi-component systems from those of binary systems. Reasonable agreement between experimental and theoretical viscosities is found.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
W. E. Acree (Jr),Thermodynamic properties of Non-electrolyte Solutions, (Academic Press, New York, 1984).
G. L. Bertrand, W. E. Acree (Jr), and T. E. Burchfield,J. Solution Chem. 12, 327 (1983); W. E. Acree Jr., and G. L. Bertrand,J. Solution Chem. 12, 755 (1983).
J. D. Pandey and B. R. Chaturvedi,Chem. Scripta 18, 227 (1981).
J. D. Pandey, N. Agrawal, Shikha Gupta, and K. Misra,Indian J. Chem. 29A, 113 (1990).
H. Eyring and M. S. John,Significant Liquid Structures, (Wiley, New York, 1969).
H. Eyring, M. S. John and R. Ryoo,Proc. Natl. Acad. Sci. (USA)77, 18 (1980).
P. J. Flory,J. Amer. Chem. Soc. 82, 1833 (1965).
P. J. Flory and A. Abc,J. Amer. Chem. Soc. 82, 1838 (1965).
J. D. Pandey, R. D. Rai, A. K. Shukla, R. K. Shukla, and N. Mishra,Indian J. Pure and Apl. Phys. 31, 54 (1993).
R. K. Dewan, V. A. Bloomfield, and P. B. Berget,J. Phys. Chem. 75, 3120, 3113 (1971).
G. Delmas and C. Jambu,Can. J. Chem. 55, 1360 (1977).
J. D. Pandey and A. D. M. David,J. Phys. Chem. 85, 3151 (1981).
S. Oswal,Can. J. Chem. 66, 111 (1988).
D. Patterson and G. Demas,Disc. Farad. Soc. 49, 98 (1970).
D. Brostow and J. S. Sochnski,J. Mater Soc. 10, 2134 (1975).
J. D. Pandey and N. Pant,J. Amer. Chem. Soc. 104, 3299 (1982).
J. D. Pandey, R. K. Shukla, A. K. Shukla and R. D. Rai,J. Chem. Soc. Farad. Trans. I 84, 1853 (1988).
J. D. Pandey, V. N. P. Srivastava, V. Vyas, and N. Pant,Indian J. Pure and Appl. Phys. 25, 467 (1987).
J. D. Pandey, N. Pant, N. Agrawal, and Shikha Gupta,Acustica 68, 225 (1989).
J. D. Pandey, R. K. Shukla, A. K. Shukla, and R. D. Rai,J. Chem. Ther. 21, 125 (1989).
J. D. Pandey,J. Phys. Chem. 93, 4627 (1989).
J. D. Pandey, R. D. Rai, and R. K. Shukla,J. Chem. Soc., Farad. Trans. I 85, 331 (1989).
M. S. Khanwalkar,Indian J. Pure and Appl. Phys. 29, 616 (1991).
T. A. Litovitz and P. B. Macedo,J. Chem. Phys. 42, 245 (1965).
H. Eyring, R. E. Powell and W. E. Roseo-veare,J. Appl. Phys. 12, 669 (1941).
G. L. Bertrand,Indian Eng. Gen. Fundam. 16, 492 (1977).
J. Timmermans,Physico-Chemical Constants of Pure Organic Compounds, (Elsevier, New York, 1950).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Pandey, J.D., Pandey, S., Gupta, S. et al. Viscosity of ternary liquid mixtures. J Solution Chem 23, 1049–1059 (1994). https://doi.org/10.1007/BF00974102
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00974102