Summary
Methacrylic acid was photopolymerised using CdS and composite, CdS/HgS and CdS/TiO2, colloidal semiconductor particles as initiators. The previously proposed photoinitiation mechanism involving the photogenerated positive hole in the valence band of the CdS colloid was confirmed by the electron scavenging action of TiO2. The effect of pH on the course of the polymerisation was investigated and is discussed.
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Popović IG, Katsikas L, Müller U, Velickovic JS, Weller H (1994) Makromol. Chem. 195: in press
Weller H (1993) Angew. Chem. Int. Ed. Engl. 32: 41
Spanhel L, Haase M, Weller H, Henglein A (1987) J. Am. Chem. Soc. 109: 5649
McNeill IC, Zulfiqar M, (1978) J. Polym. Sci. 16: 3201
Hässelbarth A, Eychmüller A, Eichberger R, Giersig M, Mews A, Weller H, (1993) J. Phys. Chem. 97: 5333
O'Regan B, Moser J, Anderson MA, Grätzel M (1990) J. Phys. Chem. 94: 8720
Brandrup J, Immergut EH (eds) (1989) Polymer Handbook, Third Edition, J. Wiley & Son, New York, pp. VII-10
Spanhel L, Weller H, Henglein A (1987) J. Am. Chem. Soc. 109, 6632
Blauer K (1960) Trans. Faraday Soc. 56: 606
Karaputadse TM, Kurilova AI, Topchiev DA, Kabanov VA (1972) Vysokmol. Soedin. B 14: 323
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Popović, I.G., Katsikas, L. & Weller, H. The photopolymerisation of methacrylic acid by colloidal semiconductors. Polymer Bulletin 32, 597–603 (1994). https://doi.org/10.1007/BF00973907
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DOI: https://doi.org/10.1007/BF00973907