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4-Nitrophenylhydrazones of partially formylated polystyrene, their properties and crosslinking

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Summary

The title polymers were prepared as potential non-linear optical materials with a degree of substitution 3–13 mole %. During UV-irradiation and/or heating near the glass transition temperature these polymers crosslink through the hydrazone groups and their UV-vis absorption band diminishes. Degrees of crosslinking of swollen samples were estimated. A possibility of simultaneous crosslinking and poling of these polymers is discussed.

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References

  1. Lee K-S, Samoc M, Prasad PN (1992) Polymers for Photonic Applications. In: Allen G (ed) Comprehensive Polymer Science, First Suppl., Pergamon Press, Oxford (p 407)

    Google Scholar 

  2. Kmínek I, Brynda E, Schnabel W (1991) Eur Polym J 227: 1073

    Google Scholar 

  3. Buckley A, Choe E, DeMartino R, Leslie T, Nelson G, Stamatoff J, Stuetz D, Yoon H (1986) Polym Mater Sci Eng 54: 502

    Google Scholar 

  4. Brynda E, Koropecký I, Kmínek I, Nešpůrek S, Schnabel W, Polym Adv Technol, in press

  5. Ilavský M (1982) Macromolecules 15: 782

    Google Scholar 

  6. Kahovec J (1981) Polym Bull 4: 731

    Google Scholar 

  7. Smith PAS (1966) The Chemistry of Open-chain Organic Nitrogen Compounds, vol II, p 151, Benjamin WA, New York

    Google Scholar 

  8. Condorelli G, Costanzo LL, Giuffrida S, Pistara S (1975) Z Phys Chem Neue Folge 96: 97

    Google Scholar 

  9. Smith PA (1965) The Chemistry of Open-chain Organic Nitrogen Compounds, vol I, p 298, Benjamin WA, New York

    Google Scholar 

  10. Dušek K (1988) Polymer Networks. In: Pouchlý J, Lednický F, Raab M (Eds) Principles of Polymer Physics in Solid State (in Czech), vol 2, p 1, Institute of Macromolecular Chemistry, Prague

    Google Scholar 

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06, Prague 6, Czech Republic

    Ivan Kmínek & Stanislav Nešpůrek

Authors
  1. Ivan Kmínek
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  2. Stanislav Nešpůrek
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Kmínek, I., Nešpůrek, S. 4-Nitrophenylhydrazones of partially formylated polystyrene, their properties and crosslinking. Polymer Bulletin 32, 573–580 (1994). https://doi.org/10.1007/BF00973904

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  • DOI: https://doi.org/10.1007/BF00973904

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