Abstract
Copolymers of α-methyl styrene and 2-ethylhexyl acrylate were prepared in a benzene solution. The presence of the copolymers were confirmed by solubility, IR and NMR tests. The molecular weight and the polydispersity of the polymers were estimated by GPC. The copolymers obtained were blended with paraffinic and naphthenic base oils. The viscosity, the viscosity index (VI) the Q value as well as the stability to shear and oxidation were obtained for these blends. The results are compared with the results obtained with an oil blend containing a commonly used high temperature additive. Two of the copolymers obtained have shown to be good alternatives for specific applications.
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.References
A. Schilling,Les Huiles pour Moteurs et Graissage des Moteurs, (I.F.P. Éditions Technip, Paris, 1962).
Rohm and Hass, U.S. Patent, 2,091,627 (1937).
W. L. Van Horne,Ind. Eng. Chem., 5, 952 (1949).
Lubrication and Lubricants E. R. Braithwaite, ed., (Elsevier, Amsterdam, (1962), p. 130.
J. Denis, J. C. Lavragne and G. Parc,Revue de l'Institut Français du Pétrol XXIV No. 10, 1229 (1969).
R. C. Gunther,Lubrication, (Brothers and Swinfen, London, 1972), p. 263.
J. P. Arlie, J. Denis, and G. Parc,Inst. Petroleum, (I. P. Paper, London 1975).
J. P. Arlie, J. Denis, and G. Parc,Inst. Petroleum, (I. P. Paper, London, 1975).
M. Robin,Revue de l'Institut Français du Pétrole XXXIII No. 5, 78 (1978).
Exxon, U.S. Patent, 4,139,480 (1978).
P. Neudserfl,5 th International Colloquium on Additives for Lubricating and Operational Fluids, Vol. 11, W. J. Bartz, ed., (Technische Akademie, Esslingen Ostfieldern Germany 1986).
Rohm GMBH, U.S. Patent, 4,149,984 (1979).
Rohm GMBH, U.S. Patent, 4,290,925 (1981).
Phillips Petroleum, U.S. Patent, 3,554,911 (1971).
Lubrizol, U.S. Patent, 3,702,300 (1976).
BASF AG., German Patent, 3,106,959 (1982).
R. J. A., Eckert and D. F. Cavey,.Lubrification Sci.,1, 65 1988.
M. Otto, F. L. Miller, A. J. Blackwood, and G. H. B. Davis,Oil Gas J. 33, 98 (1934).
Esso Research and Engineering, U.S. Patent, 2,130,507 (1938).
R. M. Thomas, J. C. Zimmer, L. B. Turner, R. Rosen, and P. K. Frolich,Ind. Eng. Chem. 32, 299 (1940).
Monsanto, German Patent, 900,736 (1950).
Shell Oil, U.S. Patent, 3,554,911 (1969).
Shell Oil, Great Britain Patent, 1,370,093 (1970).
Shell Oil, U.S. Patent, 3,835,059 (1972).
Dupont De Nemours, U.S. Patent, 3,790,480 (1972).
Shell Oil, U.S. Patent, 3,763,044 (1973).
Shell Oil, U.S. Patent, 3 772 196, (1973).
Shell Oil, U.S. Patent, 4 116 917, (1978).
Standard Oil of Indiana, U.S. Patent, 4,136,047 (1979).
G. T. Spiers, J. E. Johnson and G. Verstrate,5th International Colloquiumon Additives for Lubricating and Operational Fluids, Vol. 11, W. J. Bartz, ed. (Technische Akademie, Essling Ostfieldern Germany, 1986).
Shell Oil, U.S. Patent, 4,788 361 (1988).
R. Marsden,Lubrication Sci. 1, 265 (1988).
G. Ver Strate and M. J. Struglinski,Polymer Material Sci. Eng. 61, 252, (1989).
M. Shidara, M. Tsutsumi, Y. Tanabe, and I. Hattori,Jpn. Kokai Tokkyo Koho,29 452, (1990).
N. Kim Yoshi and Y. Yugi,Jpn. Kokai Hoha 22 (1988).
J. Denis, B. Sillion and R. Léger; French Patent (pending), 2,613,371.
R. Stambaugh,The Chemistry and Technology of Lubricants, (Blackie Group, Glasgow, in press).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bataille, P., Sharifi-Sanjani, N. & Evin, E. Preparation and characterization of a viscosity index improver for naphthenic and paraffinic base oils. J Solution Chem 23, 325–338 (1994). https://doi.org/10.1007/BF00973553
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00973553