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Reaction of platinum (II) hydrides with carbenium ions

  • Z. N. Parnes
  • G. D. Kolemnikova
  • M. I. Kalinkin
  • D. Kh. Shaapuni
  • S. M. Markosyan
  • D. I. Kursanov
Organic and Biological Chemistry
  • 24 Downloads

Conclusions

  1. 1.

    Platinum hydrides are the active donors of the hydride ion with respect to\(Ph_3 \mathop C\limits^ \oplus \).

     
  2. 2.

    The phosphine complexes of Ni, Pd, and Pt exhibit catalytic activity in the ionic hydrogenolysis of alcohols, the Pt complexes being the most active.

     

Keywords

Alcohol Platinum Catalytic Activity Hydride Phosphine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    M. I. Kalinkin, Z. N. Parnes, D. Kh. Shaapuni, and D. N. Kursanov, Dokl. Akad. Nauk SSSR,219, 1367 (1974).Google Scholar
  2. 2.
    N. C. Deno, N. Friedman, and J. D. Hodge, J. Am. Chem. Soc.,84, 4713 (1962).Google Scholar
  3. 3.
    J. Chatt and B. L. Shaw, J. Chem. Soc., 5081 (1962).Google Scholar
  4. 4.
    G. W. Parshall, J. Am. Chem. Soc.,89, 1822 (1967).Google Scholar

Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • Z. N. Parnes
    • 1
  • G. D. Kolemnikova
    • 1
  • M. I. Kalinkin
    • 1
  • D. Kh. Shaapuni
    • 1
  • S. M. Markosyan
    • 1
  • D. I. Kursanov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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