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Behavior of the13C lines in the ESR spectra of 3,6-di-tert-butyl-2-oxyphenoxyl with intramolecular hydrogen atom migration

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Study has been made of the effect of unpaired electron hyperfine interaction with the13C nucleus on the ESR spectrum of 3,6-di-tert-butyl-2-oxyphenoxyl.

  2. 2.

    The spin density distribution has been calculated for the radical under both rapid and slow exchange, and13C hfi constants obtained for various positions.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, The Academy of Sciences of the USSR, Moscow

    A. I. Prokof'ev, S. P. Solodovnikov, N. N. Bubnov & A. S. Masilimov

Authors
  1. A. I. Prokof'ev
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  2. S. P. Solodovnikov
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  3. N. N. Bubnov
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  4. A. S. Masilimov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2488–2493, November, 1976.

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Prokof'ev, A.I., Solodovnikov, S.P., Bubnov, N.N. et al. Behavior of the13C lines in the ESR spectra of 3,6-di-tert-butyl-2-oxyphenoxyl with intramolecular hydrogen atom migration. Russ Chem Bull 25, 2318–2322 (1976). https://doi.org/10.1007/BF00973386

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  • DOI: https://doi.org/10.1007/BF00973386

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