Abstract
Solubility measurements of several nonpolar gases (He, Ne, Ar, Kr, Xe, H2, N2, CH4, C2H4, C2H6, CF4, SF6, and CO2) in 2,2,2-trifluoroethanol at 25°C and 101.33 kPa partial pressure of gas are reported. Gibbs energy for the solution process at 25°C is evaluated from the experimental values of the solubility of gases expressed as mole fraction. Lennard-Jones 6–12 pair potential parameters for 2,2,2-trifluoroethanol are estimated by using the scaled particle theory (SPT); and experimental solubilities are compared with those calculated from the values of these parameters through the SPT model.
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References
R. A. Pierotti,J. Phys. Chem. 67, 1840 (1963).
R. A. Pierotti,J. Phys. Chem. 69, 281 (1965).
E. Wilhelm and Battino,J. Chem. Phys,55, 4012 (1971).
J. Carnicer, F. Gibanel, J. S. Urieta, C. Gutiérrez Losa,Rev. Aca Zaragoza 34, 113 (1979).
B. Naim and S. Baer,Trans. Faraday Soc. 59, 2735 (1963).
A. Cooney and K. W. Morcom,J. Chem. Thermodyn. 20, 735 (1988).
E. Wilhelm,CRC Crit. Rev. Anal. Chem. 16, 129 (1985).
T. Tominaga, R. Battino, H. K. Gorowara and R. D. E. Dixon,J. Chem. Eng. Data 31, 175 (1986).
S. Bo, R. Battino and E. Wilhelm,J. Chem. Eng. Data 38, 611 (1993).
N. J. P. Maris and L. I. Stiel,Ind. Eng. Chem. Process Des. Dev. 24, 183 (1985).
F. Gibanel, M. C. López, F. M. Royo, V. Rodríguez, and J. S. Urieta,J. Solution Chem. 23, 1247 (1994).
R. C. Reid, J. M. Prausnitz and B. E. Poling,The Properties of Gases and Liquids, (McGraw-Hill, New York, 1986).
R. Battino,Fluid Phase Equilibria 15, 231 (1984).
H. L. Clever and R. Battino, inTechniques of Chemistry, Vol. 8, Part 1 (Wiley, New York, 1975).
R. A. Pierotti,Chem. Rev. 76, 717 (1976).
H. Reiss, H. L. Frisch, and J. L. Lebowitz,J. Chem. Phys. 31, 369 (1959).
A. L. McClellan,Tables of Experimental Dipole Moments Vol. 3, (Rahara Enterprises, El Cerrito, 1989).
M. Denda, H. Touhara, and K. Nakanishi,J. Chem. Thermodyn. 19, 539 (1987).
R. Palepu, J. Clarke,Termochim. Acta. 156, 359–363 (1989).
J. O. Hirschfelder, C. F. Curtiss, and R. B. Bird,Molecular Theory of Gases and Liquids (Wiley, New York, 1966).
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Mainar, A.M., Pardo, J., Royo, F.M. et al. Solubility of nonpolar gases in 2,2,2-trifluoroethanol at 25°C and 101.33 kPa partial pressure of gas. J Solution Chem 25, 589–595 (1996). https://doi.org/10.1007/BF00973087
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DOI: https://doi.org/10.1007/BF00973087