Abstract
ΔE NT values for 2-pyrrolidinone and N-methylbenzenesulfonamide solvent systems, in which the solvents were benzyl alcohol, 1,4-dioxane and hexamethylphosphoric triamide, were determined over the whole mole fraction range. The study was carried out at 30 and 50°C. The ΔE NT values were positive for all of these systems, with the exception of the 2-pyrrolidinone-hexamethylphosphoric triamide system, which was slightly negative. The results are discussed in terms of intermolecular interactions and preferential solvation.
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K. Dimroth, C. Reichardt, T. Siepmann, and F. Bohlmann,Liebigs Ann. Chem. 661, 1 (1963).
T. Mattila, P. Ruostesuo, V. Rukajärvi, P. Pirilä-Honkanen, and S. Kurkisuo,Thermochim. Acta 132, 235 (1988).
P. Pirilä-Honkanen and P. Ruostesuo,Thermochim. Acta 156, 129 (1989).
P. Ruostesuo, P. Pirilä-Honkanen, and V. Rukajärvi,J. Solution Chem. 21, 229 (1992).
P. Pirilä-Honkanen and P. Ruostesuo,Thermochim. Acta 184, 65 (1991).
G. M. Dyson and P. May,May's Chemistry of Synthetic Drugs, (Longmans, London, 1959), p. 474.
J. A. Walmsley, E. J. Jacob, and H. B. Thompson,J. Phys. Chem. 80, 2745 (1976).
J. A. Walmsley,J. Phys. Chem. 82, 2031 (1978).
J. Jadzyn, J. Malecki, and J. Jadzyn,J. Phys. Chem. 82, 2128 (1978).
R. König and G. Malewski,Spectrochim. Acta 24, 219 (1968).
D. D. Perrin, W. L. F. Armarego, and D. R. Perrin,Purification of Laboratory Chemicals, (Pergamon, London, 1964).
R. M. Moriarty,J. Org. Chem. 30, 600 (1965).
K. Hess and H. Frahm,Ber. Dtsch. Chem. Ges. 71, 2627 (1983).
C. Reichardt,Solvents and Solvent Effects in Organic Chemistry, 2nd, rev. and enl. edn., (VCH, Weinheim, 1990), p. 363–371, 408–409.
E. Dutkiewicz, A. Jakubowska, and M. Dutkiewicz,Spectrochim. Acta 48, 1409 (1992).
J. R. Haak and B. F. N. Engberts,Rec. Trav. Chim. Pays-Bas 105, 307 (1986).
A. N. Hambly and R. H. Laby,Aust. J. Chem. 14, 318 (1961).
Z. B. Maksimovic, C. Reichardt, and A. Spiric,Z. Anal. Chem. 270, 100 (1974).
S. Balakrisnan and A. J. Easteal,Aust. J. Chem. 34, 933 (1981).
J. G. Dawber, J. Ward, and R. A. Williams,J. Chem. Soc., Faraday Trans. 1,84, 713 (1988).
I. A. Koppel and J. B. Koppel,Org. React. (Tartu) 20, 523 (1983).
P. Pirilä-Honkanen,J. Solution Chem. 24, 641 (1995).
E. Bosch, M. Roses, K. Herodes, I. Koppel, I. Leito, I. Koppel, and V. Taal,J. Phys. Org. Chem. (1996) In Press.
L. N. Patnaik and B. Sahu,J. Solution Chem. 23, 1317 (1994).
Y. Marcus,J. Chem. Soc. Faraday 85, 381 (1989).
J. A. Soroka and K. B. Sorok,J. Phys. Org. Chem. 4, 592 (1991).
Y. Marcus,Chem. Soc. Rev. 409 (1993).
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Pirilä-Honkanen, P.L. Thermodynamic and spectroscopic properties of 2-pyrrolidinones. 7. ΔE NT for binary solvent mixtures of 2-pyrrolidinone andN-methylbenzenesulfonamide at 30 and 50°C. J Solution Chem 25, 555–565 (1996). https://doi.org/10.1007/BF00973085
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DOI: https://doi.org/10.1007/BF00973085