Skip to main content
SpringerLink
Log in

Variation ofE T(30) polarity and the Kamlet-Taft solvatochromic parameters with composition in alcohol-alcohol mixtures

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Solvatochromic parameter values, namely ET(30) polarity, and Kamlet-Taft π*, α and β, in alcoholic binary mixtures have been determined and correlated with solvent composition. The studied mixtures involve ethanol, methanol, 2-methoxyethanol and 1,2-ethandiol. Theoretical and semiempirical equations which embody preferential solvation of solvatochromic probes and allow the accurate interpolation of solvatochromic parameters are proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. G. Dawber, J. Ward, and R. A. Williams,J. Chem. Soc. Faraday Trans. I 84, 713 (1988).

    Google Scholar 

  2. E. Bosch and M. Rosés,J. Chem. Soc. Faraday Trans. 88, 3541 (1992).

    Google Scholar 

  3. K. Dimroth, Ch. Reichardt, T. Siepmann, and F. Bohlmann,Liebigs Ann. Chem. 661, 1 (1963).

    Google Scholar 

  4. Ch. Reichardt,Solvents and Solvent Effects in Organic Chemistry, 2nd edn. (VCH, Weinheim, 1988).

    Google Scholar 

  5. M. J. Kamlet, J-L. M. Abboud, and R. W. Taft,J. Am. Chem. Soc. 99, 6027 (1977).

    Google Scholar 

  6. J. Ortega, M. Rosés, and E. Bosch,J. Solution. Chem. 23, 735 (1994).

    Google Scholar 

  7. R. D. Skwierczynski and K. A. Connors,J. Chem. Soc. Perkin Trans. II 467 (1994).

    Google Scholar 

  8. M. J. Kamlet, J-L. M. Abboud, and R. W. Taft,Prog. Phys. Org. Chem. 13, 485 (1983).

    Google Scholar 

  9. Y. Marcus and Y. Migron,J. Phys. Chem. 95, 400 (1991).

    Google Scholar 

  10. Y. Marcus,Ion Solvation (Wiley, Chichester, 1985).

    Google Scholar 

  11. M. J. Kamlet, J-L. M. Abboud, M. H. Abraham, and R. W. Taft,J. Organic Chem. 48, 2877 (1983).

    Google Scholar 

  12. R. M. C. Gonçalves, A. M. N. Simoes, L. M. P. C. Albuquerque, M. Rosés, C. Ràfols, and E. Bosch,J. Chem. Res. (S), 214 (1993); (M), 1380 (1993).

  13. J. L. Beltrán, G. Centeno, A. Izquierdo, and M. D. Prat,Talanta 39, 981 (1992).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departament de Química Analítica, Universitat de Barcelona, Diagonal 647, 08028, Barcelona, Spain

    M. Rosés, J. Ortega & E. Bosch

Authors
  1. M. Rosés
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Ortega
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Bosch
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rosés, M., Ortega, J. & Bosch, E. Variation ofE T(30) polarity and the Kamlet-Taft solvatochromic parameters with composition in alcohol-alcohol mixtures. J Solution Chem 24, 51–63 (1995). https://doi.org/10.1007/BF00973049

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00973049

Key Words

Search

Navigation