Skip to main content
Log in

Excess molar volumes and molar refraction of 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone+water water from 5 to 45°C

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The excess molar volumes and molar refractionsR 12 of 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone (DMPU)+water have been determined over the entire mole fraction range at 10° intervals from 5 to 45°C and at atmosphere pressure. The excess volumes are all negative and they become more positive with increase of temperature. Limiting partial molar volumes for DMPU in water and water in DMPU are also reported.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C. Yanes, P. Perez-Tejeda, E. Garcia-Pañeda, and A. Maestre,J. Chem. Soc. Faraday Trans. 88, 223 (1992).

    Google Scholar 

  2. E. Garcia-Pañeda, P. Perez-Tejeda, C. Yanes, and A. Maestre,J. Chem. Eng. Data 37 333 (1992).

    Google Scholar 

  3. E. Garcia-Pañeda, C. Yanes, J. J. Calvente, and A. Maestre,J. Chem. Soc. Faraday Trans. 90, 575 (1994).

    Google Scholar 

  4. B. J. Baker, J. Rosenfarb, and J. A. Caruso,Angew. Chem. Int. Ed. Engl. 18, 503 (1979).

    Google Scholar 

  5. J. Stroka, I. Herfort, and H. Schneider,J. Solution Chem. 19, 743 (1990).

    Google Scholar 

  6. A. Feldman and I. H. Malitson, inRecommended Reference Materials for the Realization of Physicochemical Properties, K. N. Marsh ed., (Blackwell, Oxford,1987) Chap. 15.

    Google Scholar 

  7. P. Kneisi and J. W. Zondlo,J. Chem. Eng. Data 32, 11 (1987).

    Google Scholar 

  8. G. S. Kell,J. Chem. Eng. Data 20, 97 (1975).

    Google Scholar 

  9. J. Ortega and M. I. Paz-Andrade,J. Chem. Eng. Data 31, 231 (1986).

    Google Scholar 

  10. C. J. F. Böttcher and P. Bordewijk,Theory of Electric Polarization, Vol. II, 2nd edn. (Elsevier, Amsterdam, 1978), Chap. XII.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lemos, M.C., Maestre, A. Excess molar volumes and molar refraction of 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone+water water from 5 to 45°C. J Solution Chem 24, 1197–1208 (1995). https://doi.org/10.1007/BF00972966

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00972966

Key Words

Navigation