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Temperature and composition dependence of viscosity I. Propylene carbonate-dimethoxyethane mixtures and thermodynamics of fluid flow

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Abstract

Concentration and temperature dependence of viscosity of propylene carbonate (PC)/dimethoxyethane (DME) mixtures were studied at temperatures between −45 and 25°C. Among various semiempirical ≠(x)-functions available for data analysis, only the McAllister equation fits the data precisely. Thermodynamic quantities obtained from such an analysis results in an interpretation of the structure of this binary system consistent with results from other methods.

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References

  1. R. C. Reid, J. M. Prausnitz, and T. K. Sherwood,The Properties of Gases and Liquids 3rd Ed., (McGraw Hill, New York, 1977).

    Google Scholar 

  2. D. S. Viswanath and G. Natarajan,Data Book on the Viscosity of Liquids, (Hemisphere Publishing, New York, 1989).

    Google Scholar 

  3. S. Bretsznajder,Prediction of Transport and Other Physical Properties of Fluids, (Pergamon Press, Oxford, 1971).

    Google Scholar 

  4. Y. S. Touloukian,Thermophysical Properties of Matter, Vol. 11 Viscosity, S. C. Saxena and P. Hestermans, eds. (Plenum Press, New York, 1975).

    Google Scholar 

  5. Y. S. Touloukian, K. Stephan, and K. Lucas,Viscosity of Dense Fluids, (Plenum Press, New York, 1979).

    Google Scholar 

  6. D. B. Davies and A. J. Matheson,Discuss. Faraday Soc. 43, 216 (1967).

    Google Scholar 

  7. J. Barthel, H.-J. Gores, and G. Schmeer,Ber. Bunsenges, Phys. Chem. 83, 911 (1979).

    Google Scholar 

  8. H.-J. Gores and J. Barthel,J. Solution Chem. 9, 939 (1980).

    Google Scholar 

  9. J. Barthel, R. Wachter, and H.-J. Gores,Modern Aspects of Electrochemistry, Vol. 13, in B. E. Conway, J.O'M. Bockris, eds. (Plenum Press, New York, 1979).

    Google Scholar 

  10. R. Wachter and J. Barthel,Ber. Bunsenges. Phys. Chem. 83, 634 (1979).

    Google Scholar 

  11. I. F. Swindells, J. R. Coe, and T. B. Godfrey,J. Res. Natl. Bur. Stand.,48, 1 (1952).

    Google Scholar 

  12. D. E. Gray (coordinating editor),American Institute of Physics Handbook, 3rd Edn. (McGraw Hill, New York, 1972).

    Google Scholar 

  13. J. R. van Wazer, J. W. Lyons, K. Y. Kim and R. E. Colwell,Viscosity and Flow Measurements A Laboratory Handbook of Rheology, (Interscience, New York, 1963).

    Google Scholar 

  14. M. R. Cannon, R. E. Manning, and J. D. Bell,Anal. Chem. 32, 355 (1960).

    Google Scholar 

  15. R. E. Gibson and O. H. Loeffler,J. Am. Chem. Soc. 61, 2515 (1939).

    Google Scholar 

  16. J. S. Burlew,J. Am. Chem. Soc. 62, 690 (1940).

    Google Scholar 

  17. N. Bauer and S. Z. Levin,Physical Methods of Chemistry, Vol. I, Part IV, p. 89, in A. Weissberger ed. (Wiley, New York, 1972).

    Google Scholar 

  18. N. A. Lange,Handbook of Chemistry (10th edn.), (McGraw Hill, New York, 1967).

    Google Scholar 

  19. J. B. Irving,Natl. Eng. Lat. Rep. No.630 and631, Dep. of Industry (Feb. 1977).

  20. J. Grunberg and A. H. Nissan,Nature 164, 799 (1964).

    Google Scholar 

  21. R. K. Hind, E. McLaughlin, and U. R. Ubbelohde,Trans. Faraday Soc. 62, 1112 (1966).

    Google Scholar 

  22. E. L. Henric,J. Chem. Eng. Data 11, 66 (1965).

    Google Scholar 

  23. R. A. McAllister,Am. Inst. Chem. Eng. 6, 427 (1960).

    Google Scholar 

  24. N. E. Hill,Proceed. Phys. Soc. 67 B, 149 (1954).

    Google Scholar 

  25. P. K. Katti and M. M. Chaudri,J. Chem. Eng. Data 9, 442 (1964).

    Google Scholar 

  26. J. H. Hildebrand and R. L. Scott,The Solubility of Nonelectrolytes 3rd edn., (Dover-New York, 1964).

  27. S. Glasstone, K. J. Laidler, and H. Eyring,The Theory of Rate Processes (McGraw Hill, New York, 1941).

    Google Scholar 

  28. J. F. Kinkaid, H. Eyring, and E. A. Stearn,Chem. Rev. 28, 301 (1941).

    Google Scholar 

  29. A. K. Masood, R. A. Pethrick, and F. L. Swinton,J. Chem. Soc. Faraday Trans. 72, 20 (1976).

    Google Scholar 

  30. Y. Marcus,Ion Solvation (Wiley, Chichester, 1985).

    Google Scholar 

  31. A. N. Zhitomirskii,Russ. J. Phys. Chem. 52, 1529 (1978).

    Google Scholar 

  32. S. B. Brummer and G. J. Hills,Trans. Faraday Soc. 57, 1816 (1961).

    Google Scholar 

  33. E. L. Henric and J. G. Brewer,J. Chem. Eng. Data,12, 574 (1967).

    Google Scholar 

  34. A. R. Ubbelohde,The Molten State of Matter (Wiley, Chichester, 1978).

    Google Scholar 

  35. Y. Matsuda, H. Nakashima, M. Morita and Y. Takasu,J. Electrochem. Soc. 128, 2552 (1981).

    Google Scholar 

  36. J. Barthel and F. Feuerlein,J. Solution Chem. 13, 393 (1984).

    Google Scholar 

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Barthel, J., Utz, M., Groß, K. et al. Temperature and composition dependence of viscosity I. Propylene carbonate-dimethoxyethane mixtures and thermodynamics of fluid flow. J Solution Chem 24, 1109–1123 (1995). https://doi.org/10.1007/BF00972958

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  • DOI: https://doi.org/10.1007/BF00972958

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