Abstract
The osmotic coefficients for aqueous lithium sulfate solutions were experimentally determined at 40°C. Sodium chloride served as the isopiestic standard for the calculation of osmotic coefficients. The molality ranges covered in this study correspond to about 0.1–2.5 mol-kg−1. The system of equations developed by Hamer-Wu and Pitzer were used to fit each set of osmotic coefficients. The parameters obtained from the fit were used to calculate the activity coefficients.
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References
H. F. Holmes and R. E. Mesmer,J. Solution Chem. 15, 495 (1986).
L. F. Silvester and K. S. Pitzer,J. Phys. Chem. 81, 1822 (1977).
J. Baabor, M. A. Gilchrist, and E. J. Delgado,Bol. Soc. Chil. Quim. 39, 329 (1994).
M. A. Gilchrist and B. Calvert,Bol. Soc. Chil. Quim. 34, 237, (1989).
Hamer, W. J. and Wu, Y. C.,J. Phys. Chem. Ref. Data 1, 1047 (1972).
B. R. Staples and R. L. Nuttall,J. Phys. Chem. Ref. Data 6(2), 385 (1973).
H. F. Gibbard, G. Scatchard, R. A. Rousseau, and J. L. Creek,J. Chem. Eng. Data 19, 281 (1974).
K. S. Pitzer,J. Phys. Chem. 77, 268 (1973).
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Baabor, J., Gilchrist, M.A. & Delgado, E.J. Osmotic and activity coefficients of aqueous lithium sulfate solutions at 40°C. J Solution Chem 25, 1105–1111 (1996). https://doi.org/10.1007/BF00972925
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DOI: https://doi.org/10.1007/BF00972925