Abstract
The values of the formation constants of the zinc-chlorocomplexes in LiCl media at different ionic strengths have been evaluated from literature data on perchlorate media by using the specific interaction theory, SIT. The distinction between the real or stoichiometric activity coefficient of the electrolyte ZnCl2 and the contribution from the formation of complexes in the experimentally measured mean activity coefficient, resulting from varying the ionic strength, has been made on the basis of the SIT theory. Values of the formation constant for the complexes at infinite dilution, as well as interaction and salting coefficients, are also given.
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Aparicio, J.L., Elizalde, M.P. Activity coefficient calculations applied to ZnCl2 in LiCl media. Distinction between the real activity coefficient and the effect of complexation. J Solution Chem 25, 1055–1069 (1996). https://doi.org/10.1007/BF00972921
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DOI: https://doi.org/10.1007/BF00972921