Abstract
The densities of mixtures of aqueous solutions of hydrochloric acid with solutions of cadmium chloride, copper chloride, manganese chloride, and zinc chloride have been measured at constant ionic strengths of 1.0 and 3.0 mol-kg−1 at 25°C. The density data were used to determine the volumes of mixing (ΔV m ). The volume of mixing equations of Pitzer were then fit to the resulting ΔV m data to obtain the Pitzer parameters θ MNV and ψ MNXV , which are the pressure derivatives of the free energy equation parameters.
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Kosa, S.A., Schreiber, D.R. The volumes of mixing of aqueous solutions of CdCl2, CuCl2, MnCl2, and ZnCl2 with HCl at varying ionic strength at 25°C. J Solution Chem 23, 901–910 (1994). https://doi.org/10.1007/BF00972753
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DOI: https://doi.org/10.1007/BF00972753