Journal of Solution Chemistry

, Volume 23, Issue 5, pp 561–568 | Cite as

Excess and partial excess molar volumes of 1,4-dichlorobutane with butanols at 25 and 40°C

  • C. Lafuente
  • V. Rodríguez
  • M. C. López
  • F. M. Royo
  • J. S. Urieta
Article

Abstract

From density measurements over the whole composition range at 25 and 40°C excess molar volumes for binary mixtures of 1,4-dichlorobutane with l-butanol, 2-butanol, 2-methyl-l-propanol or 2-methyl-2-propanol are calculated. VE results were fitted by the method of least squares to a smoothing equation. Excess partial molar volumes and limiting excess partial molar volumes at 25° are also calculated.

Key Words

Excess molar volumes partial excess molar volumes 1-4-dichlorobutane isomers of butanol 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    J. Pardo, V. Rodríguez, M. C. López, F. M. Royo and J. S. Urieta,J. Chem. Thermodyn.24, 113 (1992).Google Scholar
  2. 2.
    J. Pardo, V. Rodríguez, C. Lafuente, F. M. Royo and J. S. Urieta,J. Chem. Thermodyn.25, 373 (1993).Google Scholar
  3. 3.
    V. Rodríguez, C. Lafuente, M. C. López, F. M. Royo and J. S. Urieta,J. Chem. Thermodyn. 25, 679 (1993).Google Scholar
  4. 4.
    C. Lafuente, J. Pardo, V. Rodríguez, F. M. Royo and J. S. Urieta,J. Chem. Eng. Data 33, 554 (1993).Google Scholar
  5. 5.
    H. Artigas, J. Santafé, M.C. López, F. M. Royo and J. S. Urieta,J. Chem. Thermodyn.25, 1403 (1993).Google Scholar
  6. 6.
    H. Artigas, C. Lafuente, V. Rodríguez, M. C. López, F. M. Royo and J. S. Urieta,J. Chem. Thermodyn. 26, 151 (1994).Google Scholar
  7. 7.
    J. Timmermans,Physico-Chemical Constants of Pure Organic Compounds, Vol. 2 (Elsevier, Amsterdam, 1965).Google Scholar
  8. 8.
    J. A. Riddick, W. B. Bunger and T. K. Sakano, Organic Solvents,Techniques of Chemistry, 4th edition, Vol 2 (Wiley-Interscience, New York, 1986)Google Scholar

Copyright information

© Plenum Publishing Corporation 1994

Authors and Affiliations

  • C. Lafuente
    • 1
  • V. Rodríguez
    • 1
  • M. C. López
    • 1
  • F. M. Royo
    • 1
  • J. S. Urieta
    • 1
  1. 1.Departamento de Química Orgánica y Química Física, Facultad de CienciasCiudad UniversitariaZaragozaSpain

Personalised recommendations