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Activity measurements in the ternary system NaBr+NaClO4+H2O at 25°C

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Abstract

The activity coefficients of sodium bromide in the ternary system NaBr+NaClO4+H2O were determined at 25°C and constant ionic strength of 0.1, 0.5, 1, 2, and 3 mol-kg−1 from emf of the cell without, liquid junction

$$ISE - Na|NaBr(m_A ), NaClO_4 (m_B ), AgCl_{(s)} 1 Ag$$

The experimental activity coefficients were comparatively analyzed by using the Harned, Scatchard, Pitzer and Lim-HOLL treatments. All these methods are adequate for the analysis of the experimental data. The results have been compared with those of Lanier for the system: NaCl+NaClO4+H2O. The Gibbs excess energy of mixing was obtained and qualitatively interpreted in terms of ionic interactions.

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Authors and Affiliations

  1. Departmento de Química Física, Universidad de la Laguna, Tenerife, España

    F. Hernández-Luis, M. Barrera, L. Fernández-Mérida & M. Pérez

  2. Departamento de Ingeniería Química, Universidad de Antofagasta, Antofagasta, Chile

    H. R. Galleguillos

Authors
  1. F. Hernández-Luis
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  2. M. Barrera
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  3. H. R. Galleguillos
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  4. L. Fernández-Mérida
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  5. M. Pérez
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Hernández-Luis, F., Barrera, M., Galleguillos, H.R. et al. Activity measurements in the ternary system NaBr+NaClO4+H2O at 25°C. J Solution Chem 25, 219–229 (1996). https://doi.org/10.1007/BF00972691

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  • DOI: https://doi.org/10.1007/BF00972691

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