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Salting coefficients of fluorobenzoic acids

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Abstract

The Setschenow parameter and thermodynamic parameters of transfer of 2-, 3- and 4-fluorobenzoic acid from water to salt solution are reported. The data have been rationalized by considering the structure breaking effects of the ions of the salts, the localized hydrolysis model and the internal pressure theory.

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References

  1. S. Sugunan,Indian J. Chem. 22A, 150 (1983).

    Google Scholar 

  2. S. Sugunan,Indian J. Chem. 23A, 763 (1984).

    Google Scholar 

  3. R. Anantaraman and K. Chandramohanakumar, unpublished work.

  4. J. Setschenow,Z. Phys. Chem. 4, 117 (1989).

    Google Scholar 

  5. Dictionary of Organic Compounds, 5th edn., (Chapman and Hall, New York, 1982).

  6. H. Margenau and G. M. Murphy,Mathematics for Physics and Chemistry (D. Van Nostrand, 1956) p. 519.

  7. R. L. Kay,ACS Advances in Chemistray Series 73, 1 (1968).

    Google Scholar 

  8. Y. Marcus,Ion Solvation (Wiley, New York, 1985) p. 113.

    Google Scholar 

  9. J. O. M. Brockris, J. Bowler-Reed, and J. A. Kitchener,Trans. Faraday Soc. 47, 184 (1951).

    Google Scholar 

  10. F. A. Long and W. McDevitt,J. Am. Chem. Soc. 74, 1775 (1952).

    Google Scholar 

  11. R. L. Kay and D. F. Evans,J. Phys. Chem. 70, 2325 (1966).

    Google Scholar 

  12. F. Franks and H. Y. Smith,Trans. Faraday Soc. 63, 2586 (1967).

    Google Scholar 

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Sugunan, S., Thomas, B. Salting coefficients of fluorobenzoic acids. J Solution Chem 23, 81–84 (1994). https://doi.org/10.1007/BF00972610

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