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Electrochemical behavior of 1,3,2,5-dioxaboraphosphorinanes and their complexes with copper(I)

  • E. V. Malova
  • T. V. Troepol'skaya
  • G. N. Nikonov
  • A. A. Karasik
Physical Chemistry
  • 19 Downloads

Abstract

P-, B-, and O-containing compounds and their complexes with copper(I) in aprotic solvents were studied for the first time by electrochemical methods (classical polarography, millicoulometry, cyclic voltammetry, and electrolysis at controlled potential). A scheme of electroreduction of dioxaboraphosphorinanes on a dropping mercury electrode is suggested, the first step of which consists of cleavage of the P-C bond, accompanied by chemical reactions. It was discovered that the electrochemical reduction of copper complexes of 1,3,2,5-dioxaboraphosphorinanes occurs with accepting of the first electrons on the lower vacant molecular orbital, determined chiefly by the ligand and not by the metal ion.

Keywords

Copper Mercury Cyclic Voltammetry Molecular Orbital Electrochemical Behavior 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • E. V. Malova
    • 1
  • T. V. Troepol'skaya
    • 1
  • G. N. Nikonov
    • 1
  • A. A. Karasik
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Science CenterAcademy of Sciences of the USSRUSSR

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