Conclusions
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1.
The position of the charge transfer band in the charge transfer complexes of ferrocene derivatives with CH2I2, CHI3, and CI4 is more a function of the nature of the polyiodomethane than of the nature of the substituent in the ferrocene molecule.
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2.
The ferrocene ionization potential was used to calculate the position of this band when experimental determination was difficult.
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Literature cited
P. Fornier and S. R. Logan, J. Chem. Soc., Faraday Trans. 1,76, 580 (1980).
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V. A. Zver'kov, Chemical Candidate's Dissertation, Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow (1983).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 711–714, March, 1988.
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Velichko, F.K., Balabanova, L.V., Vasil'eva, T.T. et al. Charge transfer complexes of ferrocene derivatives with polyiodomethanes. Russ Chem Bull 37, 610–612 (1988). https://doi.org/10.1007/BF00965393
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DOI: https://doi.org/10.1007/BF00965393