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C5-homologization of ubiquinone-9 and ubiquinone-10 using sulfur-containing synthons

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A seven-stage method has been developed for the transformation of ubiquinone-9 to ubiquinone-10 using sulfur-containing synthons as the key step; the most effective synthon was found to be prenyl phenyl sulfide. The analogous homologization of solanesol and decaprenol using an isoprenyl trans-C5-hydroxysulfone was also examined.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. B. Veselovskii, A. M. Moiseenkov, T. M. Filippova, E. A. Obol'nikova & G. I. Samokhvalov

  2. “Vitamins” Scientific Industrial Association, Moscow

    A. B. Veselovskii, A. M. Moiseenkov, T. M. Filippova, E. A. Obol'nikova & G. I. Samokhvalov

Authors
  1. A. B. Veselovskii
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  2. A. M. Moiseenkov
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  3. T. M. Filippova
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  4. E. A. Obol'nikova
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  5. G. I. Samokhvalov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 695–701, March, 1988.

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Veselovskii, A.B., Moiseenkov, A.M., Filippova, T.M. et al. C5-homologization of ubiquinone-9 and ubiquinone-10 using sulfur-containing synthons. Russ Chem Bull 37, 594–599 (1988). https://doi.org/10.1007/BF00965388

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  • DOI: https://doi.org/10.1007/BF00965388

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