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Reaction of electrochemically generated radical anions with phosphorylated ureas

  • G. K. Budnikov
  • O. Yu. Kargina
  • S. V. Lapshina
  • É. A. Gurylev
  • Z. Ya. Latypov
Physical Chemistry
  • 22 Downloads

Conclusions

  1. 1.

    In the presence of phosphorylated ureas, oxygen, nitrobenzene, benzophenone, and anthracene are reduced in DMF on a mercury cathode according to the ECE mechanism, and the rate constants k2 and activation energies of the included chemical reaction were calculated.

     
  2. 2.

    Based on the kinetic data, the scheme of the process with included protonation of the radical anion in which any of the hydrogen atoms in the NH fragments of the PU molecules can participate was proposed.

     

Keywords

Oxygen Hydrogen Mercury Urea Activation Energy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • G. K. Budnikov
    • 1
    • 2
  • O. Yu. Kargina
    • 1
    • 2
  • S. V. Lapshina
    • 1
    • 2
  • É. A. Gurylev
    • 1
    • 2
  • Z. Ya. Latypov
    • 1
    • 2
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan BranchAcademy of Sciences of the USSRUSSR
  2. 2.V. I. Ul'yanov-Lenin Kazan State UniversityUSSR

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