Skip to main content
SpringerLink
Log in

Dissociation of 4-tert-butoxy-2, 6-di-tertbutylphenoxyl and antioxid ative activity of phenols with alkoky substituents

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    4-tert-Butoxy-2,6-di-tert-butylphenoxyl radicals in benzene solution cleave the tert-butyl radical to give 2,6-di-tert-butyl- 1,4-benzoquinone.

  2. 2.

    A kinetic analysis of the autooxidation scheme, inhibited by a sterically hindered phenol, shows that decomposition of the phenoxyl leads to an impairment of all of the indices of the antioxidative activity of a phenolic antioxidant.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. N. M. Émanuél', E. T. Denisov, and Z. K. Maizus, Chain Oxidation Reactions of Hydrocarbons in the Liquid Phase [in Russian], Nauka, Moscow (1965).

    Google Scholar 

  2. E. T. Denisov, Usp. Khim.,42, 361 (1973).

    Google Scholar 

  3. V. A. Roginskii, Vysokomol. Soedin.,24, 1000 (1982).

    Google Scholar 

  4. V. A. Belyakov, E. L. Shanina, V. A. Roginskii, and V. B. Miller, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2685.

  5. V. I. Rubtsov, V. A. Roginskii, V. B. Miller, and G. E. Zaikov, Kinet. Ratal.,21, 612 (1980).

    Google Scholar 

  6. E. A. Giezen, Degradation and stabilization of polymers. AKZO Research Laboratories and Institute of Chemical Physics Academy of Sciences USSR. Proceedings of the First Conference, Moscow (1975), p. 91.

  7. V. D. Pokhodenko, Phenoxyl Radicals [in Russian], Naukova Dumka, Kiev (1969).

    Google Scholar 

  8. V. A. Roginskii and V. A. Belyakov, Dokl. Akad. Nauk SSSR,237, 1404 (1977).

    Google Scholar 

  9. V. A. Roginskii, Kinet. Ratal.,23, 500 (1982).

    Google Scholar 

  10. E. T. Denisov, Usp. Khim.,47, 1090 (1978).

    Google Scholar 

  11. V. S. Pudov and A. L. Buchachenko, Usp. Khim.,39, 130 (1970).

    Google Scholar 

  12. M. B. Neiman, in monograph: Chemical Kinetics and Chain Reactions [in Russian], Nauka, Moscow (1966), p. 409.

    Google Scholar 

  13. C. R. H. I. De Jonge, H. J. Hageman, W. G. B. Haijsmans, and W. J. Mijs, J. Chem. Soc., Perkin Trans. 2,1973, 1276.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    V. A. Roginskii, V. Z. Dubinskii & V. B. Miller

Authors
  1. V. A. Roginskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Z. Dubinskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. B. Miller
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2808–2812, December, 1981.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Roginskii, V.A., Dubinskii, V.Z. & Miller, V.B. Dissociation of 4-tert-butoxy-2, 6-di-tertbutylphenoxyl and antioxid ative activity of phenols with alkoky substituents. Russ Chem Bull 30, 2341–2344 (1981). https://doi.org/10.1007/BF00963707

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00963707

Keywords

Search

Navigation