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Preparation of BIS(o- and m-carboranyl) disulfides by reaction of sulfur chlorides with o- and m-carboranes in presence of A1C13

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A simple method was proposed for obtaining the bis(9-o- and 9-m-carboranyl) disulfides from the o- and m-carboranes and S2C12 in the presence of A1C13, and also a simple method for reducing the latter to the 9-o- and 9-m-carboranylthiols.

  2. 2.

    When the o- and m-carboranes are reacted with SC12 in the presence of A1C13 the main products are the bis (o- and m-carboranyl) disulfides.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. I. Zakharkin & I. V. Pisareva

Authors
  1. L. I. Zakharkin
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  2. I. V. Pisareva
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2794–2796, December, 1981.

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Zakharkin, L.I., Pisareva, I.V. Preparation of BIS(o- and m-carboranyl) disulfides by reaction of sulfur chlorides with o- and m-carboranes in presence of A1C13 . Russ Chem Bull 30, 2328–2330 (1981). https://doi.org/10.1007/BF00963702

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  • DOI: https://doi.org/10.1007/BF00963702

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