Skip to main content
SpringerLink
Log in

Reaction of hydridohydroxodecacarbo-nyltriangulotriosmium with pyridine

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The following occurs when HOs3(OH)(CO)10 is reacted with pyridine or deuteropyridine: replacement of both bridge ligands in the osmium cluster, cleavage of the C-H or C-D bond, and migration of the H or D atom into the metal ring.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. G. W. Parshall, Ace. Chem. Res.,3, 139 (1970).

    Google Scholar 

  2. I. V. Barinov, Dissertation, Moscow (1974).

  3. W. Keim, J. Organomet. Chem.,14, 179 (1968).

    Google Scholar 

  4. C. Ch. Yin and A. J. Deeming, J. Chem. Soc. Dalton Trans.,1974, 1013.

  5. C. Ch. Yin and A. J. Deeming, J. Chem. Soc. Dalton Trans.,1975, 2091.

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Branch of the Academy of Sciences of the USSR, Krasnoyarsk

    V. A. Maksakov, E. D. Korniets, L. K. Kedrova & S. P. Gubin

Authors
  1. V. A. Maksakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. D. Korniets
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. K. Kedrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. P. Gubin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2793–2794, December, 1981.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Maksakov, V.A., Korniets, E.D., Kedrova, L.K. et al. Reaction of hydridohydroxodecacarbo-nyltriangulotriosmium with pyridine. Russ Chem Bull 30, 2327–2328 (1981). https://doi.org/10.1007/BF00963701

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00963701

Keywords

Search

Navigation