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Electrochemical oxidation and reduction of ferrocenophanes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The first step of the electrochemical reduction of ferrocenophanones and ferrocenophanediones is the formation of radical-anions.

  2. 2.

    6,6-Di(cyanomethyl)-[3]-ferrocenophane and bis[(6-cyanomethyl)-[3]-ferrocenophan-6-yl] are formed in the electrochemical reduction of [3]-ferrocenophan-6-one.

  3. 3.

    6,6-Di(cyanomethyl)- and 6-(cyanomethyl)[3](1,1′)[3](3,3′) ferrocenophanes are formed in the electrochemical reduction of [3](1,1′)[3](3,3)-ferrocenophan-6-one.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    M. G. Peterleitner, L. I. Denisovich, A. Z. Kreindlin & M. I. Rybinskaya

Authors
  1. M. G. Peterleitner
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  2. L. I. Denisovich
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  3. A. Z. Kreindlin
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  4. M. I. Rybinskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2780–2784, December, 1981.

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Peterleitner, M.G., Denisovich, L.I., Kreindlin, A.Z. et al. Electrochemical oxidation and reduction of ferrocenophanes. Russ Chem Bull 30, 2316–2319 (1981). https://doi.org/10.1007/BF00963697

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  • DOI: https://doi.org/10.1007/BF00963697

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