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Organoboron compounds 396. Crystal and molecular structure of dipropylboryl-(2-formimidoylaminopyridinate)

  • I. A. Teslya
  • Z. A. Starikova
  • V. K. Trunov
  • T. N. Kukina
  • V. A. Dorokhov
  • B. M. Mikhailov
Physical Chemistry

Conclusions

  1. 1.

    X-ray structure analysis has been used to determine the crystal and molecular structure of dipropylboryl-(2-forminimidoylaminopyridinate).

     
  2. 2.

    In the chelate ring of dipropylboryl-(2-forminimidoylaminopyridinate), six of the π-electrons form a nonclosed five-center π-system (NCNCN), and the B-N bonds are semicoordination bonds.

     
  3. 3.

    Protonation of dipropylboryl-(2-forminimidoylaminopyridinate) takes place through the N2 atom.

     

Keywords

Molecular Structure Structure Analysis Chelate Ring Organoboron Compound 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • I. A. Teslya
    • 1
    • 2
  • Z. A. Starikova
    • 1
    • 2
  • V. K. Trunov
    • 1
    • 2
  • T. N. Kukina
    • 1
    • 2
  • V. A. Dorokhov
    • 1
    • 2
  • B. M. Mikhailov
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow
  2. 2.All-Union Scientific-Research Institute of Chemical Reagents and Ultrapure ChemicalsUSSR

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