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NMR spectroscopic study of conjugation effects 14. NMR spectra and structure of 1-vinylazoles

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    According to1H and13C NMR spectra, the molecules of 1-vinylazoles are conformationally homogeneous.

  2. 2.

    An increase in the number of N atoms in the azole ring leads to an increase in the role of the acceptor π-induction effect in relation to the pπ conjugation in the N-vinyl fragment.

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Literature cited

  1. B. A. Trofimov, G. A. Kalabin, V. M. Bzhezovskii, N. K. Gusarova, D. F. Kushnarev, and C. V. Amosova, Reakts. Sposobn. Org. Soedin.,11, 365 (1974).

    Google Scholar 

  2. G. A. Kalabin, B. A. Trofimov, V. M. Bzhezovskii, D. F. Kushnarev, S. V. Amosova, N. K. Gusarova, and M. L. Al'pert, Izv. Akad. Nauk SSSR, Ser. Khim., 576 (1975).

  3. V. M. Bzhezovskii, G. A. Kalabin, G. A. Chmutova, and B. A. Trofimov, Izv. Akad. Nauk SSSR, Ser. Khim., 586 (1977).

  4. B. A. Trofimov, M. V. Sigalov, V. M. Bzhezovskii, G. A. Kalabin, A. I. Mikhaleva, and A. N. Vasil'ev, Khim. Geterotsikl. Soed., 360 (1978).

  5. M. V. Sigalov, G. A. Kalabin, A. I. Mikhaleva, and B. A. Trofimov, Khim. Geterotsikl. Soed., 328 (1980).

  6. C. J. Martin, M. L. Martin, and S. Odiot, Org. Magn. Reson.,7, 2 (1975).

    Google Scholar 

  7. Yu. L. Frolov, N. N. Chipanina, F. S. Lur'e, D. S. D. Taryashinova, E. S. Domnina, and G. G. Skvortsova, Izv. Akad. Nauk SSSR, Ser. Khim., 1562 (1980).

  8. M. Begtrup, Acta Chem. Scand.,B28, 61 (1974).

    Google Scholar 

  9. M. Begtrup, Acta Chem. Scand.,27, 3101 (1973).

    Google Scholar 

  10. C. W. Fong, Aust. J. Chem.,33, 1763 (1980).

    Google Scholar 

  11. C. Miyajima, K. Takanashi, and K. Nishimoto, Org. Magn. Reson.,6, 417 (1974).

    Google Scholar 

  12. G. E. Maciel, J. Phys. Chem.,69, 1947 (1965).

    Google Scholar 

  13. T. Avignon, L. Bouscasse, and J. Elguero, Tetrahedron,34, 1139 (1978).

    Google Scholar 

  14. A. B. Katritsky, and R. D. Topsom, Chem. Rev.,77, 639 (1977).

    Google Scholar 

  15. E. Bouchet, C. Coquelet, and J. Elguero, J. Chem. Soc. Perkin Trans. 2, 449 (1974).

    Google Scholar 

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    M. V. Sigalov, G. A. Kalabin, A. G. Proidakov, E. S. Domnina & G. G. Skvortsova

  2. A. A. Zhdanov Irkutsk State University, USSR

    M. V. Sigalov, G. A. Kalabin, A. G. Proidakov, E. S. Domnina & G. G. Skvortsova

Authors
  1. M. V. Sigalov
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  2. G. A. Kalabin
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  3. A. G. Proidakov
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  4. E. S. Domnina
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  5. G. G. Skvortsova
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Additional information

Translated from Izvestiya Adademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2676–2680, December, 1981.

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Sigalov, M.V., Kalabin, G.A., Proidakov, A.G. et al. NMR spectroscopic study of conjugation effects 14. NMR spectra and structure of 1-vinylazoles. Russ Chem Bull 30, 2226–2229 (1981). https://doi.org/10.1007/BF00963676

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  • DOI: https://doi.org/10.1007/BF00963676

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