Conclusions
A method has been devised for obtaining inorganic supports (silica gels) with nearly equal values of the density of surface-bound organosilicon modifiers containing electron-donor (diphenylphosphine) groups. These silica gels can be used to obtain a series of comparable“heterogenized” metal-complex catalysts.
Similar content being viewed by others
Literature cited
F. R. Hartley and P. N. Vezey, Adv. Organomet. Chem.,15, 189 (1977).
Yu. J. Ermakov (Yermakov), Catal. Rev.,13, 77 (1976).
V. M. Vdovin, N. A. Pritula, V. E. Fedorov, and G. K. Fedorova, Transactions of Fifth All-Union Conference on Chemistry and Applications of Organosilicon Compounds [in Russian], Tbilisi (1980), No. 1, p. 69.
K. G. Allum, R. D. Hancock, I. V. Hovell, S. Mckenzie, R. C. Pitkethly, and P. J. Robinson, J. Organomet. Chem.,87, 203 (1975).
L. T. Zhuravlev and A. V. Kiselev, Kolloidn. Zh.,24, 22 (1962).
V. I. Lygin and A. V. Kiselev, Kolloidn. Zh.,23, 299 (1961).
A. V. Kiselev and V. I. Lygin, Infrared Spectroscopy of Surface Compounds [in Russian], Nauka, Moscow (1972), p. 137.
L. Boksanyi, O. Liardon, and E. K. Kovats, Adv. Colloid. and Interface,6, No. 2, 95 (1976).
K. Issleib, Pure Appl. Chem.,9, 205 (1964).
H. P. Boehm, M. Schneider, and H. Wistube, Angew. Chem.,77, 622 (1965).
M. Capka, Inorg. Metallorg. Chem.,7, 347 (1977).
M. Noel, J. C. Combert, J. Leroux, and H. Normant, C, Rend. Acad. Sci.,268, 1152 (1969).
J. W. Ryan, G. K. Menzie, and J. L. Speier, J. Amer. Chem. Soc.,82, 3601 (1960).
M. Bartholin, Ch. Graillat, A. Guyot, G. Coudurier, J. Bandiera, and C. Naccache, J. Mol. Catal.,3, 17 (1977/1978).
Experimental Methods in Adsorption and Molecular Chromatography [in Russian], Izd. Mosk. Univ., (1973), p. 108.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2663–2668, December, 1981.
Rights and permissions
About this article
Cite this article
Vdovin, V.M., Fedorov, V.E., Pritula, N.A. et al. Metal-complex catalysts coordinately fixed on inoeganic supports with the aid of organosilicon Compounds. 1. Some laws of synthesis of modified inorganic supports. Russ Chem Bull 30, 2215–2219 (1981). https://doi.org/10.1007/BF00963674
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00963674