Conclusions
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1.
The cis addition of hydrogen to the triple bond occurs when 2-pentyne is hydrogenated.
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2.
The specific activity of a zeolite in the hydrogenation of pentynes is determined by the higher ionization potential of the cation.
Literature cited
Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, and T. A. Isakova, Kinet. Katal.,13, 1101 (1972).
V. V. Kharlamov, V. I. Garanin, D. B. Tagiev, Kh. M. Minachev, and A. A. Goryachev, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 673.
Kh. M. Minachev, V. V. Kharlamov, and N. G. Kharatishvili, Izv. Akad Nauk SSSR, Ser. Khim.,1979, 97.
V. V. Kharlamov, N. G. Kharatishvili, Yu. A. Borisov, P. I. Slyunyaev, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim.,1980, 1497.
Kh. M. Minachev, V. V. Kharlamov, V. I. Garanin, and D. B. Tagiev, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 1709.
Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, and M. A. Kapustin, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2673.
J. K. Bond and P. B. Wells, Catalysis. Physical Chemistry of Heterogeneous Catalysis [Russian translation], Mir, Moscow (1967), p. 351.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2396–2398, October, 1981.
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Kharlamov, V.V., Kharatishvili, N.G. & Minachev, K.M. Hydrogenation of pentynes on cationic forms of zeolite Y. Russ Chem Bull 30, 1976–1977 (1981). https://doi.org/10.1007/BF00963445
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DOI: https://doi.org/10.1007/BF00963445