Conclusions
The reaction of chlorine fluosulfate with perfluorocarboxylic acid nitriles, using an equimolar ratio of the reactants and the corresponding order of mixing them, gives N-chloroiminoperfluoroacyl fluosulfates in high yield, while the use of excess chlorine fluosulfate gives perfluoroacyl fluosulfates and pyrosulfuryl difluoride.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2370–2373, October, 1981.
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Fokin, A.V., Studnev, Y.N., Rapkin, A.I. et al. Reaction of chlorine fluosulfate with perfluorocarboxylic acid nitriles. Russ Chem Bull 30, 1953–1955 (1981). https://doi.org/10.1007/BF00963434
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DOI: https://doi.org/10.1007/BF00963434