Conclusions
The copper salts of some hydrates of fluorinatedα-keto acids with a ligand:copper ratio=1∶1 were obtained, which is the first example of a fluoroalkyl gem-dihydroxy group taking part in the formation of an ionic bond with a transitionmetal cation.
Literature cited
Beilstein, Vol. 3, Berlin (1921), p. 623.
I. L. Knunyants, V. V. Shokina, and V. V. Tyuleneva, Dokl. Akad. Nauk SSSR,169, 594 (1966).
V. I. Saloutin, I. A. Piterskikh, K. I. Pashkevich, M. I. Kodess, and I. Ya. Postovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1980, 2403.
V. I. Saloutin, K. I. Pashkevich, I. A. Piterskikh, M. N. Rudaya, and I. Ya. Postovskii, Izv. Akad. Nauk SSSR, Ser. Khim.,1980, 2625.
L. J. Bellamy, New Data on Infrared Spectra of Complex Molecules [Russian translation], Mir, Moscow (1971), pp. 135, 231.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2368–2370, October, 1981.
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Saloutin, V.I., Piterskikh, I.A., Pashkevich, K.I. et al. Copper salts of hydrates of fluorinated α-keto acids. Russ Chem Bull 30, 1950–1952 (1981). https://doi.org/10.1007/BF00963433
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DOI: https://doi.org/10.1007/BF00963433