Synthesis of five-membered heterocyclic compounds from perfluoro-α-lactam

  • D. P. Del'tsova
  • N. P. Gambaryan
  • E. I. Mysov
Organic Chemistry


1-(Perfluoro-tert-butyl)-3,3-bis(trifluoromethyl)aziridin-2-one enters into cyclic addition reactions with carbonyl compounds and with nitriles, forming oxazolidones and imidazolones. Cyclic addition to perfluoro-α-lactam takes place, depending on the type of reagent, with rupture of any of the bonds in the three-membered ring.


Carbonyl Nitrile Carbonyl Compound Heterocyclic Compound Trifluoromethyl 
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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • D. P. Del'tsova
    • 1
  • N. P. Gambaryan
    • 1
  • E. I. Mysov
    • 1
  1. 1.A. N. Nesmeyanov Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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