Geminal systems. 15. Chemical properties of N-chloro-N-alkoxy-N-tert-alkylamines

  • V. G. Shtamburg
  • V. F. Rudchenko
  • Sh. S. Nasibov
  • I. I. Chervin
  • A. P. Pleshkova
  • R. G. Kostyanovskii
Organic Chemistry


N-chloro-N-alkoxy-N-tert-alkylamines react exclusively with CN and SCN and partially with Et and AcO to give nucleophilic substitution products at the nitrogen atom. These compounds react with AcO and water to give nitroso compounds, with EtS and Ph3 P to give azoxy compounds, and with AgF and AgNO3 to give products of more complex transformations.


Nitrogen Chemical Property Nitrogen Atom AgNO3 Nucleophilic Substitution 
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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • V. G. Shtamburg
    • 1
  • V. F. Rudchenko
    • 1
  • Sh. S. Nasibov
    • 1
  • I. I. Chervin
    • 1
  • A. P. Pleshkova
    • 1
  • R. G. Kostyanovskii
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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