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Geminal systems. 15. Chemical properties of N-chloro-N-alkoxy-N-tert-alkylamines

  • V. G. Shtamburg
  • V. F. Rudchenko
  • Sh. S. Nasibov
  • I. I. Chervin
  • A. P. Pleshkova
  • R. G. Kostyanovskii
Organic Chemistry

Conclusions

N-chloro-N-alkoxy-N-tert-alkylamines react exclusively with CN and SCN and partially with Et and AcO to give nucleophilic substitution products at the nitrogen atom. These compounds react with AcO and water to give nitroso compounds, with EtS and Ph3 P to give azoxy compounds, and with AgF and AgNO3 to give products of more complex transformations.

Keywords

Nitrogen Chemical Property Nitrogen Atom AgNO3 Nucleophilic Substitution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1982

Authors and Affiliations

  • V. G. Shtamburg
    • 1
  • V. F. Rudchenko
    • 1
  • Sh. S. Nasibov
    • 1
  • I. I. Chervin
    • 1
  • A. P. Pleshkova
    • 1
  • R. G. Kostyanovskii
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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